微波催化合成四苯基卟啉  

The Synthesis of Tetraphenyl-Porphyrin(TPP) Under Microwave Irradiation

作　　者：王征远[1] 江桂英[1] 

机构地区：[1]扬州职业大学轻纺工程系,江苏扬州225002

出　　处：《精细化工中间体》2004年第1期38-39,共2页Fine Chemical Intermediates

摘　　要：在有机溶剂体系中,利用微波催化苯甲醛、吡咯合成四苯基卟啉。最佳反应条件为:二甲苯溶剂100ml,对硝基苯甲酸催化剂1.8g,苯甲醛0.02mol、吡咯0.02mol,微波功率210W,辐射时间15min,产率达到52 9%,经重结晶,双组分紫外光谱法测定四苯基卟啉纯度达96%。The synthetic methods of meso-teraphenylporphyrin(TPP) under microwave irradiation in organic solvent were researched. The optimum reaction conditions are as follows: 1.8g p-nitrobentoic acid as the catalyst in 100?ml xylene, 0.02mol phenylformaldehyde, 0.02?mol pyrrole, 210W microwave power and 15?min microwave irradiation. The yield reachs 52.9%. The purity of the product for TPP was 96% for recrystallization by double Wave-UV valuing.

关 键 词：四苯基卟啉 微波催化 合成 

分 类 号：TQ251.3[化学工程—有机化工]