无催化微波消解法快速测定炼油污水中的化学需氧量  被引量:5

Quick measuring chemical oxygen demand of refinery water with microwave digestion apparatus in catalyzer free system

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作  者:林培喜[1] 周锡堂[1] 李德豪[1] 陈少华[1] 

机构地区:[1]茂名学院化工学院,广东茂名525000

出  处:《应用化工》2004年第1期45-47,共3页Applied Chemical Industry

摘  要:研究了无催化剂微波消解法测定炼油污水中的CODCr,详细考查了微波消解的有关条件,得到的最佳消解条件为:加入(S∶P=8∶1)混酸占总体积的55%,消解时间为12min,取样量为3.0mL,重铬酸钾溶液(浓度为0.15~2.0mol/L)3.0mL,功率720W。在最佳消解条件下跟踪一段时间,结果和回流法相符,相对误差在5%内。本法具有消解时间短,试剂用量少等优点,适合COD值在150~2000mg/L的炼油污水的测定。The paper has reported a new technique that is used to measuring COD_(Cr) of refinery water with microwave digestion apparatus using no catalyzers, the optimal digesting conditions are: the ratio of sulfuric acid to phosphoric acid: S∶P=8∶1, and the use level of acid is 55 percent of total liquid; digesting time: 12 min; water sample dosage: 3.00 mL; dosage and concentration of potassium bichromate: 3.00mL, (0.15~0.20mol/L); power of microwave: 720W. It has been found that according to the optimal condition,after following a period of time,the results are true to those of reflux,the errors are not beyond 5%.The technique has advantages because of speediness and low consumption,and is adapt to measure refinery water when COD_(Cr) is at range of 150~2000 especially.

关 键 词:炼油污水 COD 微波消解 

分 类 号:O653[理学—分析化学]

 

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