应用平均球近似理论计算锂盐有机溶液电导率  

CALCULATION OF CONDUCTANCE FOR ORGANIC SOLUTIONS OF LITHIUM SALT USING MEAN SPHERICAL APPROXIMATION THEORY

作　　者：韩景立[1] 

机构地区：[1]清华大学化学工程系,北京100084

出　　处：《化工学报》2004年第2期268-270,共3页CIESC Journal

基　　金：清华大学基础研究基金资助项目 (No .2 0 0 115 0 0 7)

摘　　要：The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.The molar conductance of electrolytes LiPF 6-PC(propylene carbonate), LiPF 6·2DG(diglyme)-PC and LiPF 6·PMDETA(pentamethyldiethylenetriamine)-PC were calculated by using mean spherical approximation(MSA). The range of concentration was from 0.001 mol·L -1 to 1 mol·L -1. The dissociation equilibrium of salts is taken into account. The mean relative deviations were 5.6%, 4.2% and 4.7%, respectively.

关 键 词：平均球近似理论 电导率 锂盐 有机溶液 

分 类 号：TM911[电气工程—电力电子与电力传动]