热解聚间苯二胺基超级电容器电极材料的研究  

Study on the supercapacitor electrode materials based on the pyrolytic poly(m - phenylenediamine)

作　　者：陈慧颖[1] 白续铎[1] 王淑红[1] 赵晓峰[2] 汪成[1] 王哲[1] 温殿忠[2] 

机构地区：[1]黑龙江大学化学化工学院,黑龙江哈尔滨150080 [2]黑龙江大学电子工程学院,黑龙江哈尔滨150080

出　　处：《黑龙江大学自然科学学报》2004年第1期122-125,共4页Journal of Natural Science of Heilongjiang University

基　　金：黑龙江省自然科学基金资助项目(E1225)

摘　　要：间苯二胺在氧化剂存在下聚合成聚间苯二胺,然后在高温下热解得到一次热解聚间苯二胺(PPDAN-1),PPDAN-1在KOH存在下进一步高温烧蚀,得到二次热解聚间苯二胺(PPDAN-2),以PPDAN-2为电极材料制成超级电容器,通过对电容器的恒流充放电测定结果表明,它是一种良好的电极材料,其比容量可达到189F·g-1。Poly(m-phenylenediamine) was synthesized by oxidation polymerization of m-phenylenedi-amine. The first pyrolytic poly (m-phenylenediamine) (PPDAN-1) was obtained by treating poly (m-phenylenediamine) under high temperature and the second pyrolytic poly (m-phenylenediamme) (PPDAN-2) was prepared by further heating PPDAN - 1 in the presence of KOH and then used for supercapactior active electrode material. The charge/discharge results show that PPDAN-2 exhibits good electrochemical performances and the specific capacitance is 189F·g-1.

关 键 词：聚间苯二胺 热裂解 超大容量电容器 

分 类 号：TM53[电气工程—电器]