PSt/(SiO_2-PBA)复合粒子的设计与合成  

DESIGN AND PREPARATION OF PSt/ (SiO_2-PBA) COMPOSITE PARTICLE

作　　者：段明[1] 胡星琪[1] 李富生[1] 董兆雄[2] 

机构地区：[1]西南石油学院化学化工学院,四川新都610500 [2]西南石油学院石油工程学院,四川新都610500

出　　处：《高分子材料科学与工程》2004年第1期97-100,共4页Polymer Materials Science & Engineering

基　　金：油气藏地质及开发国家重点实验室开放基金资助项目(PLN0120)

摘　　要：采用Winzor提出的界面自由能计算方法对核壳型聚苯乙烯/聚丙烯酸丁酯复合粒子的四种常见形态进行了计算,计算结果表明形成正向核壳复合粒子的界面自由能变化最小。定性地分析了硅溶胶粒子吸附在聚苯乙烯乳胶粒表面的可能性。采用种子半连续乳液聚合法制备了聚苯乙烯/(二氧化硅-聚丙烯酸丁酯)复合粒子,利用扫描电镜和透射电镜证实了最终合成的粒子形态,燃烧实验结果表明:该复合乳液具有较好的阻燃性。Firstly, the change in free energy for each possible morphology of PSt/(SiO_2-PBA) core-shell latex was calculated by the method provided by Winzor. The result shows that the free energy of the core-shell morphology changes less. Secondly, the possibility of adsorption of Silica particles on the PSt particles was analyzed. Finally, the composite latex was prepared by seeded semi-continuous emulsion polymerization. And the composite particle's morphology was confirmed by transmission electron microscope. The result based on the cabinet method shows that the composite latex has flame-retardant performance.

关 键 词：聚苯乙烯 聚丙烯酸丁酯 核壳型 种子半连续乳液聚合法 硅溶胶 阻燃性 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业] TQ323.4