A Novel Hydrogen-bonded Three-dimensional Network Complex Containing Nickel  

作　　者：WANGLi LIJuan WANGEn-bo 

机构地区：[1]InstituteofPolyoxometalateChemistry,EacultyofChemistry,NortheastNormalUniversity,Changchun130024,P.R.China

出　　处：《Chemical Research in Chinese Universities》2004年第2期127-130,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(No.2 0 1710 10)

摘　　要：A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a=13.853(3) nm, b=9.6892(19) nm, c=13.732(3) nm, α=90.00°, β=115.52(3)°, γ=90.00°, Z=3, R 1=0.0786, wR 2=0.1522.A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a=13.853(3) nm, b=9.6892(19) nm, c=13.732(3) nm, α=90.00°, β=115.52(3)°, γ=90.00°, Z=3, R 1=0.0786, wR 2=0.1522.

关 键 词：STACKING Hydrogen-bonding interaction Three-dimensional(3D) network 2 6-Pyridinedicarboxylic acid 

分 类 号：O63[理学—高分子化学]