丙二酰肼席夫碱及其金属配合物合成与表征  

Synthesis and Characterization a Schiff Base of Propanedioyldihydrazide and Their Complexes

作　　者：屈永年[1] 李贵华[1] 周明华[1] 

机构地区：[1]湖北省郧阳医学院基础部,湖北十堰442000

出　　处：《化学与生物工程》2004年第2期54-56,共3页Chemistry & Bioengineering

摘　　要：合成了丙二酰肼缩双水杨醛席夫碱配体及与Cu(Ⅱ)、Ni(Ⅱ)和Zn(Ⅱ)的金属配合物,用元素分析、IR、摩尔电导和电子光谱对所有化合物进行了表征,对席夫碱配体还进行了1HNMR和MS结构表征,给出了化合物可能的空间结构。The Schiff base of propanedioyldihydrazide with two molecular of salicyladehyde and its Cu(Ⅱ), Ni(Ⅱ), Zn(Ⅱ) complexes have been synthesized. The compounds have been characterized by elemental analysis, IR, molar conductivity and electronic absorption spectrum. The Schiff base ligand has been further ascertained by 1H NMR and MS. The coordination state and possible structure in the compounds are given.

关 键 词：丙二酰肼 席夫碱 金属配合物 表征 电子光谱 空间结构 草酰胺 Cu Ni ZN 摩尔电导 

分 类 号：Q946.88[生物学—植物学] O623.732[理学—有机化学]