Synthesis and magnetic properties of one-dimensional Mn(Ⅱ)complexes linked by dithiooxalato  

Synthesis and magnetic properties of one-dimensional Mn(II) complexes linked by dithiooxalato

作　　者：CUI Jianzhong, SHI Wei, CHENG Peng, CHEN Xufang, LIAO Daizheng, YAN Shiping, JIANG Zonghui & WANG GenglinDepartment of Chemistry, Nankai University, Tianjin 300071, China Correspondence should be addressed to Cheng Peng (e-mail: pcheng@ nankai.edu.cn) 

出　　处：《Chinese Science Bulletin》2003年第9期859-861,共3页

基　　金：supported by the National Natural Science Foundation of China(Grant Nos.90101028 and 50173011);the Natural Science Foundation of Tianjin(Grant No.013801611)and the TRAPOYT of MOE,China

摘　　要：Three dithiooxalato (Dto) bridging one-dimensional Mn(Ⅱ) complexes [Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag- netic interactions between the Mn(Ⅱ) ions.Three dithiooxalato (Dto) bridging one-dimensional Mn(II) complexes [Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag-netic interactions between the Mn(II) ions.

关 键 词：一维结构 锰配合物 合成 反铁磁性 Dto 二硫代草酰胺 

分 类 号：O482.5[理学—固体物理]