以二茂铁二羧酸为配体的锌配位聚合物[Zn(Py)_2L]_n的合成与晶体结构  

Synthesis and Crystal Structure of Zinc Coordination Polymer with Ferrocenedicarboxylic Acid as Ligand

作　　者：冷思伟[1] 吴刚[1] 辛明红[1] 唐璐璐[1] 朱广山[1] 范勇[1] 史苏华[1] 

机构地区：[1]吉林大学化学学院

出　　处：《高等学校化学学报》2004年第5期817-819,共3页Chemical Journal of Chinese Universities

基　　金：吉林大学无机合成与制备化学国家重点实验室资助

摘　　要：The title compound [Zn(Py) 2L] n(L=1,2′-ferrocenedicarboxylate) was synthesized under mild conditions and its crystal structure was characterized. It crystallizes in a monoclinic system, space group C2/c with the cell parameters a=1.683 0(5) nm, b=1.380 4(3) nm, c=1.746 2(3) nm, β=108.78(2)°, V=3.840 8(15) nm 3, Z=8, M r=485.52, T=293(2) K, D c=3.359 Mg/m 3, μ= 4.073 mm -1, F(000)=3 872, R 1=0.040 1, wR 2=0.113 2. The compound exhibits an unusual one-dimensional chain consisting of two zigzag chains.The title compound [Zn(Py) 2L] n(L=1,2′-ferrocenedicarboxylate) was synthesized under mild conditions and its crystal structure was characterized. It crystallizes in a monoclinic system, space group C2/c with the cell parameters a=1.683 0(5) nm, b=1.380 4(3) nm, c=1.746 2(3) nm, β=108.78(2)°, V=3.840 8(15) nm 3, Z=8, M r=485.52, T=293(2) K, D c=3.359 Mg/m 3, μ= 4.073 mm -1, F(000)=3 872, R 1=0.040 1, wR 2=0.113 2. The compound exhibits an unusual one-dimensional chain consisting of two zigzag chains.

关 键 词：二茂铁二羧酸 锌配位聚合物 [Zn(Py)2L]n 合成 晶体结构 无机-有机杂化微孔晶体材料 

分 类 号：O614.241[理学—无机化学] TB383[理学—化学]