新颖一维配位聚合物[Ni(3,5-pdc)(H_2O)_4]·(H_2O)的合成与晶体结构  

Synthesis and Crystal Structure of a Novel One-Dimensional Coordination Polymer, [Ni(3,5-pdc)(H_2O)_4]·(H_2O)

作　　者：李春辉[1] 司书峰[1] 王如骥[1] 李亚栋[1] 

机构地区：[1]清华大学化学系,北京100084

出　　处：《无机化学学报》2004年第5期536-538,共3页Chinese Journal of Inorganic Chemistry

基　　金：国家杰出青年科学基金资助项目(No.20025102)。

摘　　要：The crystal structure of the compound was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/n, a=1.136 1(3)nm, b=0.709 8(2) nm, c=1.459 7(4) nm, β=107.538(4)°, V=1.122 4(6) nm3, Dc=1.858 g·cm-1, Z=4, F(000)=648, R1=0.0264, wR2=0.0665. CCDC: 224880.The crystal structure of the compound was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/n, a=1.136 1(3)nm, b=0.709 8(2) nm, c=1.459 7(4) nm, β=107.538(4)°, V=1.122 4(6) nm3, Dc=1.858 g·cm-1, Z=4, F(000)=648, R1=0.0264, wR2=0.0665. CCDC: 224880.

关 键 词：一维配位聚合物 [Ni(3 5-pdc)(H2O)4·(H2O) 合成 晶体结构 氯化镍 3 5-吡啶二甲酸 水热法 镍配合物 超分子化学 

分 类 号：O614.813[理学—无机化学] O641.3[理学—化学]