配合物[Eu(Ⅲ)(TFPB)_3bpy]的晶体结构和发光性质(英文)  

Crystal Structure and Luminescent Properties of the Complex [Eu(Ⅲ)(TFPB)_3bpy]

作　　者：郭俊芳[1] 张洪杰[1] 符连社[1] 孟庆国[1] 

机构地区：[1]中国科学院长春应用化学研究所稀土化学与物理重点实验室,长春130022

出　　处：《无机化学学报》2004年第5期543-546,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20171043;No.20131010;No.20121701);973项目(No.G1998061307);863项目(No.2002AA302105,2002AA324080)资助项目。

摘　　要：The crystal structure of Eu(TFPB)3bpy [TFPB: 4,4,4-trifluoro-1-phenyl-1,3- butanedione, bpy: 2,2′-bipyridyl] has been determined by single crystal X-ray diffraction and the coordination geometry of Eu atom is a square antiprism. The complex can give the characteristic luminescence of Eu3+ upon UV excitation. CCDC: 224879.The crystal structure of Eu(TFPB)3bpy [TFPB: 4,4,4-trifluoro-1-phenyl-1,3- butanedione, bpy: 2,2′-bipyridyl] has been determined by single crystal X-ray diffraction and the coordination geometry of Eu atom is a square antiprism. The complex can give the characteristic luminescence of Eu3+ upon UV excitation. CCDC: 224879.

关 键 词：銪配合物 晶体结构 发光性质 Eu(Ⅲ)(TFPB)3bpy 4 4 4-三氟-1-苯基-1 3-丁二酮 2 2'-二吡啶 

分 类 号：O614.338[理学—无机化学] O641.4[理学—化学]