四丁基氢氧化鏻(TBPH)的制备及其催化性质  

Preparation and Catalytic Properties of Tetra-n-butylphosphonium Hydroxide(TBPH)

作　　者：吴通好[1] 杨胥微[1] 杨洪茂[1] 姜玉子[1] 

机构地区：[1]吉林大学化学学院,长春130023

出　　处：《高等学校化学学报》2004年第4期737-739,共3页Chemical Journal of Chinese Universities

基　　金：吉林省科委项目 (批准号 :90 10 42 )资助

摘　　要：Quaternary phosphonium hydroxide(TBPH) is a very effective catalyst for rearrangement polymerization of organosloxanes. Such as octamethylcyclotetrasiloxane, may be polymerized to a linear dimethylsiloxane polymer by TBPH. In this paper it was found that this kind of catalysts exhibited a stronger basicity than quaternary ammonium hydroxides for a transient reaction. Methyltetramer polymerized at 90—100 ℃ with about 0.01% of the silanolate of TBPH. TBPH was synthesized and applied in the production of smell-less silicone oil.Quaternary phosphonium hydroxide(TBPH) is a very effective catalyst for rearrangement polymerization of organosloxanes. Such as octamethylcyclotetrasiloxane, may be polymerized to a linear dimethylsiloxane polymer by TBPH. In this paper it was found that this kind of catalysts exhibited a stronger basicity than quaternary ammonium hydroxides for a transient reaction. Methyltetramer polymerized at 90—100 ℃ with about 0.01% of the silanolate of TBPH. TBPH was synthesized and applied in the production of smell-less silicone oil.

关 键 词：四丁基氢氧化鏻 制备 催化性质 瞬时聚合 催化剂 硅油 TBPH 有机硅氧烷 

分 类 号：O634.41[理学—高分子化学] O643.36[理学—化学]