二苯醚四甲酸二酐的合成  

Synthesis of Tetracarboxydiphthalic Ether Dianhydride

作　　者：王正平 张丽丽 王坚[1] 

机构地区：[1]哈尔滨工程大学化工学院,哈尔滨150001

出　　处：《精细化工原料及中间体》2004年第5期26-27,32,共3页Fine Chemical Industrial Raw Materials & Intermediates

摘　　要：本文介绍了以4-氯代苯酐为原料,采用1,2,4-三氯苯作溶剂制备二苯醚四甲酸二酐(ODPA),并讨论了不同催化剂及其加量、反应时间和提纯工艺对ODPA产率的影响。In this paper, the synthesis methods of tetracarboxydiphthalic ether dianhydride (ODPA)was introduced, which was prepared with 4-chlorophthalic anhydride. And 1,2,4-trichlorobenzene acted as solvent. At the same time, the effect factors to the yield of ODPA were discussed, which concluded different kinds of catalyst and their amount, reacting time and purification technics.

关 键 词：二苯醚四甲酸二酐 合成方法 4-氯代苯酐 ODPA 催化剂 反应时间 

分 类 号：TQ245.23[化学工程—有机化工]