一种新型β成核剂及其对聚丙烯结晶性能的影响  

A Novel β Nucleating Agent and Its Effect on the Crystallization Characteristics of Isotactic Polypropylene

作　　者：冯嘉春[1] 陈鸣才[2] 张秀菊[2] 郑德 焦瑛[1] 

机构地区：[1]复旦大学,上海200433 [2]中国科学院广州化学研究所,广州510650 [3]广东炜林纳功能材料有限公司,广东佛山528521

出　　处：《塑料》2004年第2期35-37,79,共4页Plastics

基　　金：国家高技术研究发展计划863资助(2003AA324010)。

摘　　要：研究了一种稀土类新型β成核剂WBG对等规聚丙烯(iPP)结晶性能的影响。WAXD研究发现,WBG加入后可大大提高PP中β晶型的含量,当其加入量超过0 3%时,β晶型的含量可达90%;利用DSC考查了130℃时PP在加入WBG前后的等温结晶过程,发现WBG显著提高了PP的成核速率。从结构上看,WBG不同于目前常见的任何一种β成核剂,是一种高效的新型成核剂。A novel rare earth-containing β nucleating agent,WBG,was prepared and its influence on the crystallization characteristics of isotactic polypropylene ( iPP) was investigated.The results showed that the addition of small amounts of WBG to PP induced a rather high proportion of β modification.The relative content of β phase estimated by WAXD was up to 90% in a PP containing more than 03% (mass fraction) of the WBG.The isothermal crystallization at 130 ℃ examined by DSC revealed that theWBG accelerated the overall rate of crystallization remarkably.

关 键 词：Β成核剂 聚丙烯 结晶性能 稀土 结晶半时间 结晶速率 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]