配合物Cu(C_(15)H_(12)N_2O_3)(C_5H_5N)的合成和晶体结构  

Synthesis and Crystal Structure of Complex Cu(C_(15)H_(12)N_2O_3)(C_5H_5N)

作　　者：陈小华[1] 刘世雄[1] 

机构地区：[1]福州大学中心实验室,福州350002

出　　处：《无机化学学报》2004年第6期668-670,共3页Chinese Journal of Inorganic Chemistry

基　　金：福建省自然科学基金资助项目(No.E0110010)

摘　　要：The title coordination compound with N-substituted-salicyl Schiff ligand, Cu(C15H12N2O3)(C5H5N), has been synthesized. The coordination compound crystallizes in orthorhombic system, space group Pbca with a=2.037 62(7) nm, b=0.698 45(2)nm, c=2.508 76(9)nm, V=3.570 4(2) nm3, Z=8, F(000)=1 688, Dc=1.529 g·cm-3, Mr=410.91, hydrazine nitrogen atom from the dianionic ligand N-salicylaldehyde-N′-(4-methoxybenzoyl) hydrazone and one pyridine nitrogen atom coordinate to Cu(Ⅱ) ion, forming a distorted square plane. CCDC: 218182.The title coordination compound with N-substituted-salicyl Schiff ligand, Cu (C15H12N2O3)(C5H5N), has been synthesized. The coordination compound crystallizes in orthorhombic system, space group Pbca with a=2.037 62(7) nm, b=0.69845(2)nm, c=2.50876(9)nm, V=3.5704(2) nm(3), Z=8, F(000)=1 688, D-c=1.529 g.cm(-3), M-r=410.91, mu= 1.250 mm(-1), R=0.031 3 and wR=0.077 0. In the coordination compound, one phenolate oxygen, one carbonyl oxygen and one hydrazine nitrogen atom from the dianionic ligand N-salicylaldehyde-N'-(4-methoxybenzoyl) hydrazone and one pyridine nitrogen atom coordinate to Cu(II) ion, forming a distorted square plane.

关 键 词：配合物 N-取代水杨基Schiff碱 晶体结构 甲氧基苯甲酰肼 水杨醛缩 合成技术 

分 类 号：O625.632[理学—有机化学] O627.12[理学—化学]