Investigation of Light-harvest Material:Synthesis and Characterization of Nanometer Porphyrin Trimer  

作　　者：SHIYing-yan WANGXing-qiao LIXiang-qing ZHENGWen-qi DINGHong ZHUGuang-shan LIUGuo-fa 

机构地区：[1]CollegeofChemistry,JilinUniversity,Changchun130023,P.R.China [2]SchoolofChemistry＆Pharmaceutics,EastChinaUniversityofScienceandTechnology,Shanghai200237,P.R.China

出　　处：《Chemical Research in Chinese Universities》2004年第3期262-265,共4页高等学校化学研究（英文版）

基　　金：SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 0 710 14 )

摘　　要：ω -Bromopropylporphyrin ether synthesized from the raction of 1,3-dibromopropane as the bridge-linked reagent and 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin (H_2MHTPP) as the matrix reacts with 5,15-di(4- hydroxyphenyl)-10,20-diphenyl porphyrin( trans -H_2DHDPP) to give the title nanometer porphyrin trimer. The characterization was carried out by means of elemental analyses,UV-Vis,IR, 1H NMR and XRD.ω -Bromopropylporphyrin ether synthesized from the raction of 1,3-dibromopropane as the bridge-linked reagent and 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin (H_2MHTPP) as the matrix reacts with 5,15-di(4- hydroxyphenyl)-10,20-diphenyl porphyrin( trans -H_2DHDPP) to give the title nanometer porphyrin trimer. The characterization was carried out by means of elemental analyses,UV-Vis,IR, 1H NMR and XRD.

关 键 词：Nanometer porphyrin trimer ω -Bromopropylporphyrin ether Bridge-linking reagent 

分 类 号：O626[理学—有机化学]