固体聚合物电解质对质子交换膜燃料电池反应器的“电生”加氢特性的影响  

EFFECT OF SOLID POLYMER ELECTROLYTE ON ELECTRO-GENERATIVE HYDROGENATION BEHAVIOR OF PEMFC REACTOR

作　　者：马紫峰[1] 袁晓姿[1] 和庆钢[1] J Hagen V M Schmidt 

机构地区：[1]上海交通大学化工系,上海200240 [2]Institute fr Technische Chemie,Fachhochschule Mannheim

出　　处：《化工学报》2004年第5期833-836,共4页CIESC Journal

基　　金：国家自然科学基金 (No 2 0 0 760 2 6;No 5 0 2 3 60 10 ) ;国家 863计划 (No 2 0 0 2AA3 2 3 0 40 );上海市国际合作项目 (No 0 2 5 2 0 70 2 1)~~

摘　　要：Effect of some solid polymer electrolyte membranes,Nafion,Gore and Fuma membrane,on the electro-generative hydrogenation behavior of the PEMFC reactor was studied.Nafion membrane has demonstrated much better performance for the electro-generative hydrogenation of organic acids and enols than Gore and Fuma membrane.For Nafion membrane,the thickness and strength both influence the hydrogenation of organic acids and enols.Effect of some solid polymer electrolyte membranes, Nafion, Gore and Fuma membrane, on the electro-generative hydrogenation behavior of the proton exchange membrane fuel cell (PEMFC) reactor was studied. Nafion membrane demonstrates much better performance for the electro-generative hydrogenation of organic acids and enols than Gore and Fuma membranes. For Nafion membrane, both the thickness and strength influence the hydrogenation of organic acids and enols.

关 键 词：PEMFC 反应器 固体聚合物电解质 电生 加氢 

分 类 号：O643[理学—物理化学]