(二苯甲酰甲烷基)(环戊二烯基)二氯化钛/MgCl_2-SiO_2MAO中各组分对乙烯聚合的影响  

THE EFFECT OF CONSTITUENTS OF CpTi(dbm)Cl_2/MgCl_2-SiO_2/MAO ON ETHYLENE POLYMERIZATION

作　　者：孙敏[1] 许学翔[1] 赵伟[1] 纪洪波[1] 景振华[1] 

机构地区：[1]中国石油化工股份公司石油化工科学研究院,北京100083

出　　处：《高分子学报》2004年第3期406-409,共4页Acta Polymerica Sinica

摘　　要：研究开发了一种新型非茂负载乙烯聚合催化剂 CpTi(dbm)Cl2 MgCl2 SiO2 MAO ,并考察了该催化剂中各组分对乙烯聚合活性的影响 .结果表明 ,SiO2 不仅可以改善催化剂的流动性和分散性 ,还有益于提高催化活性 .MgCl2 对活性中心有一定化学改性作用 ;MgCl2 、SiO2 和CpTi(dbm)Cl2 的比例的变化对载体型催化剂的催化活性有一定影响作用 ;采用适量的MAO对复合载体MgCl2 SiO2 活化 ,能提高催化活性 .用ZnCl2 MAO对SiO2处理制成的复合载体催化剂CpTi(dbm)Cl2 MgCl2 ZnCl2 SiO2 MAO ,可以提高催化活性 ,“锌调”作用明显 ,随着锌化合物含量的增加 ,聚合物相对分子质量下降 ,相对分子质量分布加宽 ,并且其催化活性也增加 .MgCl2-SiO2 supported monocyclopentadienyl titanium complex containing beta-diketone ligand catalyst, CpTi(dbm)Cl-2/MgCl2-SiO2/MAO, was prepared and the effect of the content of this supported catalyst on catalytic activity was investigated. The activity is greatly influenced by the content of Ti, Mg and SiO2. The activity of the catalyst can be improved by adding SiO2 with good flowability and treating MgCl2-SiO2 with MAO, and the influence of Mg on the activity of Ti is also important for improving the catalytic activity. Another supported catalyst, CpTi(dbm)Cl-2/MgCl2-ZnCl2-SiO2/MAO, whereas SiO2 was treated by MAO and ZnCl2 previously,was prepared and its catalysis for ethylene polymerization was investigated. The activity increases with increasing the ZnCl2 in feed, while the molecular weight of polymers decreases and the molecular weight distribution broadens.

关 键 词：乙烯 聚合反应 非茂有机金属催化剂 β-二酮-茂型钛配合物 氯化镁-二氧化硅负载 催化剂 组分 

分 类 号：TQ325.12[化学工程—合成树脂塑料工业]