阴离子对构筑锌的肼配位卤族化合物的影响  

The Stabilizing Effect of Anion on the Construction of Hydrozine Bridged Znic Halides Single Crystals

作　　者：董亚杰[1] 王如骥[1] 彭卿[1] 李亚栋[1] 

机构地区：[1]清华大学化学系,原子分子纳米科学教育部重点实验室,北京100084

出　　处：《无机化学学报》2004年第7期819-823,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20025102;50028201;20151001);全国优秀博士论文基金;国家重大基础研究发展规划"973"项目(No.G19990645-03)等多项基金资助项目。

摘　　要：A series of hydrozine bridged metal halides single crystals were synthesized. Among them were [Zn(N2H4)2F2]·2H2O and [Zn(N2H4)2F]·Cl, the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with [Zn(N2H4)2Cl2]·2H2O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains. CSD: 413707, 1; 413708, 2.A series of hydrozine bridged metal halides single crystals were synthesized. Among them were [Zn(N2H4)(2)F-2](.)2H(2)O and [Zn(N2H4)(2)F]Cl-., the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with [Zn(N2H4)(2)Cl-2](.)2H(2)O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains.

关 键 词：阴离子 锌 肼配位卤族化合物 多维无穷结构 骨架结构 氢键 晶体结构 桥联双齿配体 

分 类 号：O614.241[理学—无机化学]