芳基重氮盐及其冠醚络合物的核磁共振研究(英文)  

STUDIES ON THE NUCLEAR MAGNETIC RESONANCE OF ARENEDIAZONIUM SALTS AND THEIR CROWN ETHER COMPLEXES

作　　者：孙祥玉[1] 赵瑶兴[1] 

机构地区：[1]中国科学院研究生院,北京100039

出　　处：《波谱学杂志》1993年第2期131-140,共10页Chinese Journal of Magnetic Resonance

基　　金：The Project was supported by the National Natural Science Foundation of China

摘　　要：本文报道一系列取代苯基重氮盐及其18-冠-6,二苯并-24-冠-8分子络合物的~1H和^(13)C NMR,考察它们在络合前后的化学位移变化,推测这类络合物的结构和络合成键状况。The 1H and 13C NMR of a series of arenediazomium salts and their 18-crown-6,dibenzo-24-crown-8 complexes have been recorded to deduce the structure of these complexes from the chemical shift changes before and after complex formation. The bonding of the complexes was also discussed .

关 键 词：芳基重氮盐 冠醚 络合物 NMR 

分 类 号：O641.4[理学—物理化学]