基于新型含氮配体构筑的Cu(I)配合物的合成、结构和光催化性能研究  

Synthesis, Structure and Photocatalytic Property of Cu(I) Complex Based on a New N-Containing Donor

作　　者：刘迎玉 滕家雯 曹慧 孙玉 谭鑫 苏北浩 袁刚 

机构地区：[1]通化师范学院化学学院,吉林通化

出　　处：《材料化学前沿》2018年第4期127-134,共8页Advances in Material Chemistry

基　　金：大学生创新创业训练项目编号为201710202091《新型配合物光催化材料的制备和性能研究》;吉林省科技厅青年科研基金项目(20160520172JH)的资助。

摘　　要：在水热条件下利用含氮配体(HL)和CuCl2通过自主装反应成功制备了一个新的卤化亚铜配合物,[Cu(I)2(L)(μ3?Cl)]n(1)。利用单晶X-射线衍射,粉末X-射线衍射和元素分析等手段对化合物进行了表征。晶体结构分析表明该化合物是一个具有(3,6)-连接拓扑特征的三维骨架化合物,其中有机配体以五连接的方式与金属离子成键。此外,该化合物展示出了一定光催化性能,在紫外光照射下能够在7小时内将RhB溶液降解约47%,是一种潜在的光催化材料。A new cuprous chloride complex, [Cu(I)2(L)(μ3?Cl)]n(1) has been synthesized by the self-assembly of HL ligand and CuCl2 under hydrothermal condition. It was characterized by single crystal X-ray diffraction, powder X-ray diffraction and elemental analysis. Structural analysis shows that the title complex exhibits three-dimensional framework with the (3,6)-connected topological network. In addition, the complex displays photocatalytic performance to some extent, and can degrade RhB solution by about 47% within 7 hours under ultraviolet irradiation, which indicates that it may be a potential photocatalytic material.

关 键 词：CU(I)配合物 含氮配体 水热合成 晶体结构 光催化 

分 类 号：O64[理学—物理化学]