糠醛选择性加氢成糠醇的催化及理论研究  

Catalysis and Theoretical Study on Selective Hydrogenation of Furfural to Furfuryl Alcohol

作　　者：岑洁 张云奕 

机构地区：[1]浙江师范大学含氟新材料研究所,浙江 金华

出　　处：《材料化学前沿》2020年第4期70-75,共6页Advances in Material Chemistry

摘　　要：糠醛是一种重要的生物质燃料生产的中间体。对糠醛进行选择性加氢得到糠醇是工业与生产中重要的化学反应之一。传统的Cr催化剂对环境污染大,所以急切需要开发低碳环保并且具有高选择性的催化剂来进行糠醛的选择性加氢反应。本文从实验化学和理论计算化学领域,总结了近年来部分国内外用于糠醛选择性加氢成糠醇的催化剂,并从理论化学层面揭示反应机理,为之后该反应提供实验与理论的指导与支撑。Furfural is an important intermediate in the production of biomass fuels. Selective hydrogenation of furfural to obtain furfuryl alcohol is one of the important chemical reactions in industry and production. Traditional Cr catalysts have a great environmental pollution, so there is an urgent need to develop low-carbon, environmentally friendly and highly selective catalysts for the selective hydrogenation of furfural. This article summarizes some domestic and foreign catalysts used in the selective hydrogenation of furfural to furfuryl alcohol from the fields of experimental chemistry and theoretical computational chemistry, and reveals the reaction mechanism from the theoretical chemistry level to provide experimental and theoretical guidance and support for the subsequent reaction.

关 键 词：糠醛 选择性加氢 糠醇 理论化学 

分 类 号：TQ2[化学工程—有机化工]