EICP修复Cu²⁺污染液的影响因素  

The Influence Factors of Remediation of Cu2+ Contaminated Solution by EICP

作　　者：段雨蓬 曾晨 陆海军 陈维 郑志善 

机构地区：[1]武汉轻工大学土木工程与建筑学院,湖北 武汉 [2]武汉市政工程设计研究院有限责任公司,湖北 武汉

出　　处：《土木工程》2024年第12期2314-2322,共9页Hans Journal of Civil Engineering

基　　金：2023年度湖北省教育厅科学研究计划青年人才项目(Q20231611);湖北省自然科学基金项目(2022CFA011);湖北省自然科学基金项目(2023AFD214)。

摘　　要：我国铜污染问题日益严峻,亟需环保高效的修复方法予以处理。脲酶诱导碳酸盐沉淀(Enzyme Induced Carbonate Precipitation, EICP)技术作为新型生物修复技术在重金属修复领域被广泛关注,但是对特定重金属污染(例如铜、镉等)的修复研究匮乏。文章采用EICP技术开展了一系列Cu2+污染液修复的试验研究,通过pH值、Cu2+修复率、Ca2+沉淀率、总沉淀量等修复指标,探究了EICP技术对Cu2+污染液的修复效果;分析了Cu2+污染液中Cu2+初始浓度、氯化钙浓度、脲酶提取液体积、修复时间等因素对修复效果的影响规律。结果表明:在一定条件下,EICP技术对Cu2+污染液的修复率最高可达40.03%;降低Cu2+初始浓度、增加脲酶提取液体积、适当提高氯化钙浓度、控制修复时间等均能促进铜离子污染的修复反应,其中污染液的Cu2+初始浓度为600 mg/L、脲酶提取液体积为20 mL、氯化钙浓度为1.6 mol/L、修复时间为12 h时,铜离子污染的修复效果更好,经济性更优。The copper pollution problem is becoming more and more serious in our country, which urgently needs environmental and efficient remediation methods to deal with it. Although the Enzyme Induced Carbonate Precipitation (EICP) technology has gained significant attention in the field of heavy metal remediation as a novel bioremediation technique, research on the remediation of specific heavy metal contaminants such as copper and cadmium are still deficient. A series of experimental studies were conducted in this paper utilizing EICP technology to remediate Cu2+ contaminated solution. The remediation efficiency of EICP on Cu2+ contaminated solution was investigated through remediation indicators, including pH value, Cu2+ removal ratio, Ca2+ precipitation ratio, and total precipitation amount. Additionally, the influence of factors such as the initial Cu2+ concentration in the contaminated solution, calcium chloride concentration, volume of urease extract, and remediat

关 键 词：重金属污染 EICP 铜污染 重金属修复 影响因素 

分 类 号：X70[环境科学与工程—环境工程]