反相悬浮聚合法制备AA-AMPS/HA/MMT复合吸水树脂及其性能的研究  

Preparation of AA-AMPS/HA/MMT Composite Water Absorbent Resin by Inverse Suspension Polymerization and Its Properties

作　　者：葛磊 童伟 

机构地区：[1]陕西省土地工程建设集团有限责任公司,陕西 西安 陕西地建土地工程技术研究院有限责任公司,陕西 西安 自然资源部退化及未利用土地整治工程重点实验室,陕西 西安 陕西省土地整治工程技术研究中心,陕西 西安 [2]陕西省土地工程建设集团有限责任公司,陕西 西安

出　　处：《化学工程与技术》2019年第6期489-496,共8页Hans Journal of Chemical Engineering and Technology

基　　金：陕西省土地工程建设集团内部科研项目“核壳型复合保水剂的制备及性能研究”(DJNY2018-13)。

摘　　要：本文采用反相悬浮聚合法,以丙烯酸(AA)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、腐植酸(HA-K)及膨润土(MMT)为主要原料,以环己烷为分散介质,Span80和Tween80为双分散剂,过硫酸钾KPS为引发剂,N,N-亚甲基双丙烯酰胺为交联剂,合成一种复合吸水树脂AA-AMPS/HA/MMT,并通过单因素法研究了膨润土添加量、交联剂、引发剂、中和度、温度等工艺条件对吸水树脂吸水性能的影响。结果表明:当原料的质量比为AA:AMPS:HA:MMT = 20:5:1:1.5,分散剂用量为7 wt%,中和度为65%,引发剂KPS占单体总量的0.96 wt%,交联剂MBA占单体总量的0.08 wt%,反应温度为67℃时,吸水树脂的吸水倍率最好,达到451 g/g。In this paper, the acrylic acid (AA), 2-acrylamido-2-methylpropanesulfonic acid (AMPS), humic acid (HA) and bentonite (MMT) were used as the main raw materials;cyclohexane was used as the dispersion medium, and Span80 and Tween80 were used as the dispersant;potassium persulfate KPS as the initiator and N,N-methylenebisacrylamide as crosslinker were used to synthesize a composite water-absorbent resin AA-AMPS/HA/MMT by reversed-phase suspension polymerization. The effects of the addition of bentonite, crosslinker, initiator, neutralization and temperature on the water absorption properties of the water-absorbing resin were studied by single factor method. The results showed that when the mass ratio of raw materials was AA:AMPS:HA:MMT = 20:5:1:1.5, the amount of dispersant was 7 wt%;the degree of neutralization was 65%;and the initiator KPS accounted was 0.96 wt% of the total monomer;the cross-linking agent MBA accounts for 0.08 wt%, and when the reaction temperature is 67?C, the water absorbing resin has the best water absorption ratio of 451 g/g.

关 键 词：保水剂 反相悬浮聚合 吸水树脂 

分 类 号：TQ3[化学工程]