稀土–钴单分子磁体的研究进展  

Research Progress of Lanthanide-Cobalt Single-Molecule Magnets

作　　者：郑祺 王金 

机构地区：[1]南通大学化学化工学院,江苏 南通 [2]南通市智能与新能源材料及器件重点实验室,江苏 南通

出　　处：《物理化学进展》2023年第3期187-204,共18页Journal of Advances in Physical Chemistry

摘　　要：稀土–过渡单分子磁体材料不仅磁性能优越,而且稀土和过渡金属具有良好的光、电、催化等性质,使其在高密度信息存储、量子计算以及多功能磁分子材料合成方面具有广阔的应用前景。钴离子具有较大的磁各向异性,是构筑单分子磁体的重要金属离子。因此,本文介绍了近年来典型的稀土–钴单分子磁体的研究进展。Lanthanide-transition metal complexes exhibiting single-molecule magnet behavior possess exceptional magnetic characteristics, as well as desirable optical, electrical, and catalytic properties associated with lanthanide and transition metals. These multifaceted attributes render them highly promising for applications in high-density information storage, quantum computing, and the synthesis of multifunctional magnetic molecular materials. Among the transition metal ions, cobalt ions are particularly noteworthy due to their significant magnetic anisotropy, making them pivotal for the construction of single-molecule magnets. Consequently, this study aims to provide an overview of the recent advancements in the investigation of representative lanthanide-cobalt single-molecule magnets.

关 键 词：稀土–钴单分子磁体 结构 磁性 

分 类 号：TM2[一般工业技术—材料科学与工程]