基于席夫碱配体的多核稀土配合物的研究进展  

Research Progresses of Polynuclear Lanthanide Complexes Based on Schiff Ligands

作　　者：孙程远 王金 

机构地区：[1]南通大学化学化工学院,江苏 南通 [2]南通智能与新能源材料重点实验室,江苏 南通

出　　处：《物理化学进展》2023年第4期317-331,共15页Journal of Advances in Physical Chemistry

摘　　要：稀土配位化合物在单分子磁体、磁致冷领域具有巨大的应用前景。席夫碱配体具有优良的配位能力,是构筑稀土配合物的理想配体。席夫碱配体构筑的多核稀土配合物因其优异的磁学性质引起了功能配位化学等领域众多研究者的关注。本文介绍了近年来由席夫碱配体构筑的多核稀土配位化合物在磁性方面取得的最新进展。Lanthanide coordination compounds have enormous application prospects in the fields of single molecule magnets and magnetic cooling. Schiff base ligands have excellent coordination ability and are ideal ligands for constructing lanthanide complexes. The construction of polynuclear lanthanide complexes with Schiff base ligands has attracted the attention of many researchers in functional coordination chemistry and other fields due to their excellent magnetic properties. This article introduces the latest progresses in magnetic properties of polynuclear lanthanide coordination compounds constructed from Schiff base ligands in recent years.

关 键 词：席夫碱配体 稀土配位化合物 磁弛豫 磁致冷 

分 类 号：F42[经济管理—产业经济]