四氢噻唑-2-硫酮-4-羧酸一步催化合成α-氨基膦酸酯类化合物  

Thiazolidine-2-thione-4-carboxylic Acid Catalyzed One-Pot Synthesis of α-Aminophosphonates

作　　者：卢懂 罗海燕 刘晨江[1] Dong Lu;Haiyan Luo;Chenjiang Liu(The Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region,College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi Xinjiang)

机构地区：[1]新疆大学化学化工学院,石油天然气精细化工教育部&自治区重点实验室,新疆乌鲁木齐

出　　处：《有机化学研究》2018年第2期52-56,共5页Journal of Organic Chemistry Research

基　　金：“万人计划”后备人选培养项目(No.wr2016cx0145);国家自然科学基金(No.21572195).

摘　　要：本文以四氢噻唑-2-硫酮-4-羧酸作为一种可循环的有机催化剂,在无溶剂条件下催化芳香醛、苯胺和亚磷酸三甲酯得到了一系列α-氨基膦酸酯类化合物。该方法具有环境友好、操作简单的特点。In this paper, thiazolidine-2-thione-4-carboxylic acid is used as a recyclable organic catalyst to catalyze the reaction of aromatic aldehyde, aniline and phosphite under the solvent-free conditions, and a series of α-aminophosphonates are obtained. The method is characterized by friendly environment and simplicity of operation.

关 键 词：Α-氨基膦酸酯 四氢噻唑-2-硫酮-4-羧酸 

分 类 号：O6[理学—化学]