惰性烯丙基试剂参与的不对称烯丙基化反应研究进展  

Advances in Asymmetric Allylation Reactions Involving Unactivated Allyl Reagents

作　　者：吴庚辛 张旭龙 黄艳[1] 

机构地区：[1]新疆大学化学化工学院石油天然气精细化工教育部&自治区重点实验室,新疆乌鲁木齐 [2]新疆出入境检验检疫局检验检疫技术中心,新疆乌鲁木齐

出　　处：《有机化学研究》2019年第2期80-87,共8页Journal of Organic Chemistry Research

基　　金：国家自然基金项目(No.21462042)。

摘　　要：过渡金属催化的不对称烯丙基化反应近年来已成为合成具有光学活性的手性化合物的重要方法。本文对近年来惰性烯丙基试剂如烯丙醇、胺、醚及联烯醚参与的不对称烯丙基化反应进行简要评述,并对该类反应未来发展前景及方向进行展望。Transition-metal-catalyzed asymmetric allylation reactions have become an important method for the synthesis of optically active chiral compounds in recent years.In this paper,the asymmetric allylation reactions involving unactivated allyl reagents such as allyl alcohols,amines,ethers and allenes are briefly reviewed,and the future development prospects and directions of these reac-tions are prospected.

关 键 词：不对称烯丙基化 过渡金属 惰性烯丙基试剂 

分 类 号：O62[理学—有机化学]