用于电解水的MOFs及衍生材料研究进展  

Research Progress on MOFs and Derived Materials for Electrolytic Water Splitting

作　　者：李妍琪 王超 朱加乐 孙冰冰 朱信澎 刘思鸶 张诗琦 鞠剑峰[1] 袁小磊 

机构地区：[1]南通大学化学化工学院,江苏 南通

出　　处：《有机化学研究》2024年第4期513-527,共15页Journal of Organic Chemistry Research

摘　　要：电解水制氢作为应对能源危机的一种可持续策略,已受到广泛关注。金属有机骨架(MOFs)作为一类孔隙率和结构可调、成本低廉的新型多孔材料,在电催化领域展现出巨大潜力,已被应用于多种电催化反应中并表现出优异的催化活性。近年来,随着技术的不断进步,大量基于MOFs的电催化剂相继涌现。因此,及时总结相关文献报道对于研究人员准确设计MOFs基电催化剂并深化深入理解相关反应机理具有重要意义。本文综述了单金属、双金属、复合金属、负载金属氧化物基电催化剂,以及独立MOF衍生电极和原始MOF电极在析氢反应(HER)、析氧反应(OER)和全水解反应中的应用,并对MOFs基材料在电催化领域的发展方向和应用前景进行了展望。Electrolytic water splitting for hydrogen production has been widely recognized as a sustainable strategy to address the ongoing energy crisis. Metal-organic frameworks (MOFs), a novel class of porous materials characterized by tunable porosity, adjustable structure, and low cost, have shown significant potential in the field of electrocatalysis. These materials have been applied to various electrocatalytic reactions, demonstrating good catalytic activity. In recent years, with continuous technological advancements, a large number of MOF-based electrocatalysts have emerged. Consequently, timely summarization of the relevant literature is crucial for researchers to accurately design MOF-based electrocatalysts and deepen their understanding of the related reaction mechanisms. This paper provides a comprehensive review of the applications of single-metal, double-metal, composite-metal, and supported metal oxide-based electrocatalysts, as well as freestanding MOF-derived electrodes and pristine MOFs electrodes, in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and overall water splitting reaction. Finally, the future development directions and application prospects of MOF-based material

关 键 词：电催化剂 金属有机框架(MOFs) 析氢反应(HER) 析氧反应(OER) 全水解 

分 类 号：O64[理学—物理化学]