Kinetics and Thermodynamic Studies: Adsorption of Pb, Cr and Ni Ions from Spent Lubrication Oil (SLO) Using Acid Modified Clay  

作　　者：Felix Sughnen Atsar Donald Kukwa Raymond Ahule Wuana Beatrice Arwenyo Felix Sughnen Atsar;Donald Kukwa;Raymond Ahule Wuana;Beatrice Arwenyo(Department of Chemistry, Benue State University, Makurdi, Nigeria;Department of Chemistry, University of Agriculture, Makurdi, Nigeria;Department of Chemistry, Gulu University, Gulu, Uganda)

机构地区：[1]Department of Chemistry, Benue State University, Makurdi, Nigeria [2]Department of Chemistry, University of Agriculture, Makurdi, Nigeria [3]Department of Chemistry, Gulu University, Gulu, Uganda

出　　处：《American Journal of Analytical Chemistry》2021年第5期109-120,共12页美国分析化学（英文）

摘　　要：Adsorption of Pb, Cr, and Ni ions from spent lubrication oil (SLO) by sulphuric acid modified clay (SAMC) was investigated considering the effect of contact time and temperature of the adsorption system. The removal percentage of the heavy metals was found to be temperature and contact time-dependent. Adsorption of the heavy metals increases with an increase in temperature and contact time with 95.0% - 100% adsorption recorded at the temperature of 331 K with the equilibration time of 12 hours. The thermodynamic and kinetics investigation of the adsorption process showed that the adsorption of these metals by the modified adsorbent is a spontaneous and endothermic physical adsorption process that followed the pseudo-second-order kinetic model.Adsorption of Pb, Cr, and Ni ions from spent lubrication oil (SLO) by sulphuric acid modified clay (SAMC) was investigated considering the effect of contact time and temperature of the adsorption system. The removal percentage of the heavy metals was found to be temperature and contact time-dependent. Adsorption of the heavy metals increases with an increase in temperature and contact time with 95.0% - 100% adsorption recorded at the temperature of 331 K with the equilibration time of 12 hours. The thermodynamic and kinetics investigation of the adsorption process showed that the adsorption of these metals by the modified adsorbent is a spontaneous and endothermic physical adsorption process that followed the pseudo-second-order kinetic model.

关 键 词：ADSORPTION Heavy Metals Sorption Mechanism Pseudo-Second-Order Kinetic Model 

分 类 号：O64[理学—物理化学]