Ni(II) N-(2-Pyridylmethyl)-L-Alanine) Complex: Structural Diversity and Photoluminiscent Studies  

作　　者：Bridget N. Ndosiri Emmanuel N. Nfor Jérôme Marrot Aminou Mohamadou Justin Nenwa Bridget N. Ndosiri;Emmanuel N. Nfor;Jérôme Marrot;Aminou Mohamadou;Justin Nenwa(Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé, Cameroon;Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon;Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier UMR 8180, Versailles, France;Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims (ICMR), CNRS UMR 7312, UFR des Sciences)

机构地区：[1]Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé, Cameroon [2]Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon [3]Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier UMR 8180, Versailles, France [4]Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims (ICMR), CNRS UMR 7312, UFR des Sciences

出　　处：《Crystal Structure Theory and Applications》2020年第4期63-72,共10页晶体结构理论与应用（英文）

摘　　要：A novel chiral Nickel (II) complex of N-(2-pyridylmethyl)-L-alanine (Hpyala) <b>1</b> has been prepared and structurally characterized by elemental analysis, FT-IR, UV-visible, TGA and single crystal X-ray diffraction techniques. Complex <b>1</b> crystallizes in an orthorhombic P2₁2₁2₁ space group. The nickel (II) centre in the complex adopts a distorted octahedral geometry. This compound has been seen to exhibit structural diversity resulting from the number of lattice water molecules. The photoluminescent properties of this compound which have also been investigated, indicates the potential application in luminescence.A novel chiral Nickel (II) complex of N-(2-pyridylmethyl)-L-alanine (Hpyala) <b>1</b> has been prepared and structurally characterized by elemental analysis, FT-IR, UV-visible, TGA and single crystal X-ray diffraction techniques. Complex <b>1</b> crystallizes in an orthorhombic P2₁2₁2₁ space group. The nickel (II) centre in the complex adopts a distorted octahedral geometry. This compound has been seen to exhibit structural diversity resulting from the number of lattice water molecules. The photoluminescent properties of this compound which have also been investigated, indicates the potential application in luminescence.

关 键 词：Nickel (II) Complex CHIRAL PHOTOLUMINESCENT X-Ray Diffraction 

分 类 号：O62[理学—有机化学]