Microwave Irradiation Effect on Intermolecular and Intramolecular Friedel-Crafts Acylation Reaction  

作　　者：Yutaka Okada Arisa Fujitsu 

机构地区：[1]Department of Applied Chemistry, Ritsumeikan University, Shiga, Japan

出　　处：《Green and Sustainable Chemistry》2020年第1期18-23,共6页绿色与可持续化学（英文）

摘　　要：The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had an accelerating effect on the intramolecular reaction. This enhanced intramolecular reactivity that was attributed to the high probability of close proximity between the reaction sites.The effect of microwave irradiation on the intermolecular and intramolecular Friedel-Crafts acylation of aromatic compounds was investigated. Microwave irradiation had no effect on the intermolecular reaction but had an accelerating effect on the intramolecular reaction. This enhanced intramolecular reactivity that was attributed to the high probability of close proximity between the reaction sites.

关 键 词：MICROWAVE Irradiation Effect FRIEDEL-CRAFTS REACTION CYCLIZATION 

分 类 号：O62[理学—有机化学]