Effect of Microwave Irradiation on Oximation of Acetylferrocene  

作　　者：Yutaka Okada Ryuichi Maeda Yutaka Okada;Ryuichi Maeda(Department of Applied Chemistry, Ritsumeikan University, Shiga, Japan)

机构地区：[1]Department of Applied Chemistry, Ritsumeikan University, Shiga, Japan

出　　处：《Green and Sustainable Chemistry》2021年第1期1-8,共8页绿色与可持续化学（英文）

摘　　要：Microwave-assisted reactions are an environmentally friendly approach for synthesizing organic compounds. In this study, oximation of acetylferrocene and acetophenone was conducted under both microwave irradiation and conventional heating conditions. Acetylferrocene and acetophenone were subjected to oximation under the two conditions in various solvent mixtures, and the extent of conversion was determined by </span>^{<span style="font-family:Verdana;">1</span>}<span style="font-family:Verdana;">H nuclear magnetic resonance spectroscopy. Microwave irradiation was found to accelerate the rate of oximation of both acetylferrocene and acetophenone. Acceleration of the reaction under microwave irradiation was attributed to the efficient absorption of microwaves by the ferrocene nucleus.Microwave-assisted reactions are an environmentally friendly approach for synthesizing organic compounds. In this study, oximation of acetylferrocene and acetophenone was conducted under both microwave irradiation and conventional heating conditions. Acetylferrocene and acetophenone were subjected to oximation under the two conditions in various solvent mixtures, and the extent of conversion was determined by </span>^{<span style="font-family:Verdana;">1</span>}<span style="font-family:Verdana;">H nuclear magnetic resonance spectroscopy. Microwave irradiation was found to accelerate the rate of oximation of both acetylferrocene and acetophenone. Acceleration of the reaction under microwave irradiation was attributed to the efficient absorption of microwaves by the ferrocene nucleus.

关 键 词：Microwave Irradiation Conventional Heating Ferrocene Nucleus ACETOPHENONE ACETYLFERROCENE OXIMATION 

分 类 号：O64[理学—物理化学]