Emulsion Graft Polymerization of Methyl Methacrylate onto Cellulose Nanofibers  

作　　者：Hiromu Okada Chao Zhao Yusuke Mizuta Katsumi Yoshino Ryuichi Sugimoto Hiromu Okada;Chao Zhao;Yusuke Mizuta;Katsumi Yoshino;Ryuichi Sugimoto(School of Environmental Science and Engineering, Kochi University of Technology, Kochi, Japan;Shimane Institute for Industrial Technology, Matsue, Japan)

机构地区：[1]School of Environmental Science and Engineering, Kochi University of Technology, Kochi, Japan [2]Shimane Institute for Industrial Technology, Matsue, Japan

出　　处：《Green and Sustainable Chemistry》2021年第1期9-22,共14页绿色与可持续化学（英文）

摘　　要：Methyl methacrylate (MMA) was successfully grafted onto cellulose nanofibers (CNFs) at room temperature in an emulsion system using a diethyl(1,10-<span style="font-family:;" "=""><span style="font-family:Verdana;">phenanthroline </span><i><span style="font-family:Verdana;">N</span></i>_{<span style="font-family:Verdana;">1</span>}<span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i>_{<span style="font-family:Verdana;">10</span>}<span style="font-family:Verdana;">)zinc(</span></span><span style="font-family:Verdana;">II</span><span style="font-family:Verdana;">) complex (Phen</span><span style="font-family:Verdana;">-</span><span style="font-family:Verdana;">DEZ) with oxygen as the radical initiator. The effects of reaction temperature, initiator concentration, and monomer content on the grafting reaction were investigated. The molecular weight of the non-grafted PMMA, which was produced during graft polymerization, was more than 1 million, as determined by size exclusion chromatography. The PMMA-grafted CNFs were analyzed by Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy, which confirmed the grafting of PMMA on the nanofiber surface. The study presents a strategy for the grafting of high-molecular weight PMMA onto CNFs in an emulsion system</span><span style="font-family:Verdana;"> using</span><span> Phen</span><span>-</span><span><span>DEZ and</span></span><span><span> O</span>_{<span>2</span>}<span>.</span></span>Methyl methacrylate (MMA) was successfully grafted onto cellulose nanofibers (CNFs) at room temperature in an emulsion system using a diethyl(1,10-<span style="font-family:;" "=""><span style="font-family:Verdana;">phenanthroline </span><i><span style="font-family:Verdana;">N</span></i>_{<span style="font-family:Verdana;">1</span>}<span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i>_{<span style="font-family:Verdana;">10</span>}<span style="font-family:Verdana;">)zinc(</span></span><span style="font-family:Verdana;">II</span><span style="font-family:Verdana;">) complex (Phen</span><span style="font-family:Verdana;">-</span><span style="font-family:Verdana;">DEZ) with oxygen as the radical initiator. The effects of reaction temperature, initiator concentration, and monomer content on the grafting reaction were investigated. The molecular weight of the non-grafted PMMA, which was produced during graft polymerization, was more than 1 million, as determined by size exclusion chromatography. The PMMA-grafted CNFs were analyzed by Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy, which confirmed the grafting of PMMA on the nanofiber surface. The study presents a strategy for the grafting of high-molecular weight PMMA onto CNFs in an emulsion system</span><span style="font-family:Verdana;"> using</span><span> Phen</span><span>-</span><span><span>DEZ and</span></span><span><span> O</span>_{<span>2</span>}<span>.</span></span>

关 键 词：Cellulose Nanofibers Graft Polymerization Methyl Methacrylate EMULSION DIETHYLZINC 

分 类 号：TB3[一般工业技术—材料科学与工程]