The Role of Aromatic Schiff Bases in the Dyes Techniques  

The Role of Aromatic Schiff Bases in the Dyes Techniques

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作  者:Karema Masoude Abuamer Abdussalam Ali Maihub Marei Miloud El-Ajaily Abdunnaser Mohamed Etorki Mortaja Mohamed Abou-Krisha Majda Albashir Almagani 

机构地区:[1]Chemistry Department, Faculty of Science, Benghazi University, Benghazi, Libya [2]Chemistry Department, Faculty of Science, South Valley University, Gena, Egypt [3]Chemistry Department, Faculty of Science, Tripoli University, Tripoli, Libya

出  处:《International Journal of Organic Chemistry》2014年第1期7-15,共9页有机化学国际期刊(英文)

摘  要:Anil compounds are Schiff bases derived from aniline moiety containing phenyl or substituted phenyl group, which sometimes called Azo dyes. These Schiff bases can be directly prepared from aromatic amine with aromatic carbonyl groups, which are stable and can be manipulated under different and suitable conditions. The phenomena of coordination of Schiff bases with metal ions give the Schiff bases the good advantages to be introduced in the dyes synthesis. The classification of dyes is based on the chemical structure or on the basis of the chromophoric system. The metal complex dyes are combinations of dyestuff and metal ions, in which the coordination complex can be applied or used to be improvement factors in dye techniques. The investigation and the characterization of the resulted dyes were performed by using different physical techniques. The produced dyes were applied to different fibres, such as sheep wool and goat hair with two Schiff bases synthesised from salicylaldehyde either with 2-aminophenol or 2-aminobenzyl alcohol. Also the investigation includes the effect of mordant type on the dyeing process.Anil compounds are Schiff bases derived from aniline moiety containing phenyl or substituted phenyl group, which sometimes called Azo dyes. These Schiff bases can be directly prepared from aromatic amine with aromatic carbonyl groups, which are stable and can be manipulated under different and suitable conditions. The phenomena of coordination of Schiff bases with metal ions give the Schiff bases the good advantages to be introduced in the dyes synthesis. The classification of dyes is based on the chemical structure or on the basis of the chromophoric system. The metal complex dyes are combinations of dyestuff and metal ions, in which the coordination complex can be applied or used to be improvement factors in dye techniques. The investigation and the characterization of the resulted dyes were performed by using different physical techniques. The produced dyes were applied to different fibres, such as sheep wool and goat hair with two Schiff bases synthesised from salicylaldehyde either with 2-aminophenol or 2-aminobenzyl alcohol. Also the investigation includes the effect of mordant type on the dyeing process.

关 键 词:DYES 2-AMINOPHENOL 2-Aminobenzyl Alcohol SALICYLALDEHYDE SCHIFF Bases COMPLEXATION 

分 类 号:O6[理学—化学]

 

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