Chiral-Electroactive Low-Bandgap Polymer Composite  

作　　者：Naoto Eguchi Kohsuke Kawabata Hiromasa Goto 

机构地区：[1]Faculty of Pure and Applied Sciences, Division of Material Sciences, University of Tsukuba, Tsukuba, Japan

出　　处：《Journal of Materials Science and Chemical Engineering》2017年第2期1-10,共10页材料科学与化学工程（英文）

摘　　要：Electrochemical polymerization of an isothianaphthene based monomer for low-bandgap polymer was carried out in a polymer lyotropic liquid crystal. We prepared hydroxypropyl cellulose/N,N-dimethylformamide (HPC/DMF) lyotropic liquid crystal system as an electrolyte solution to perform electrochemical polymerization of a hydrophobic monomer, although water was commonly employed as a solvent for HPC. Resultant polymer prepared in HPC/DMF shows both electro-activity and optical activity. Fourier transform infrared absorption spectroscopy measurement reveals that the resultant material is composite of HPC and polyisothianaphthene based.Electrochemical polymerization of an isothianaphthene based monomer for low-bandgap polymer was carried out in a polymer lyotropic liquid crystal. We prepared hydroxypropyl cellulose/N,N-dimethylformamide (HPC/DMF) lyotropic liquid crystal system as an electrolyte solution to perform electrochemical polymerization of a hydrophobic monomer, although water was commonly employed as a solvent for HPC. Resultant polymer prepared in HPC/DMF shows both electro-activity and optical activity. Fourier transform infrared absorption spectroscopy measurement reveals that the resultant material is composite of HPC and polyisothianaphthene based.

关 键 词：Electrochemical POLYMERIZATION CONJUGATED Polymer Isothianaphthene HYDROXYPROPYL CELLULOSE Composite 

分 类 号：O6[理学—化学]