Electrochemical and Surface Characterization Studies of 2-amino-6-methyl-5-oxo-4-phenyl-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile Compound on Copper in 2 M HNO₃  

作　　者：Ahmed M. Eldesoky[1] Azza M. Attia[1] Omayma E. Ahmed[1] Mohamed A. Abo-Elsoud[1] 

出　　处：《Journal of Materials Science and Chemical Engineering》2019年第12期71-86,共16页材料科学与化学工程（英文）

摘　　要：The corrosion hindrance of Cu in 2.0 M HNO3 solution by 2-amino-6-methyl-5-oxo-4-phenyl-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile compound has been studied, using Potentiodynamic Polarization (PP), AC Impedance (EIS), Electrochemical Frequency Modulation (EFM) techniques. Also, EIS test was utilized to confirm the corrosion protection mechanism. 2-amino-6-methyl-5-oxo-4-phenyl-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile compound is suggested as a mixed kind inhibitor. SEM and EDX investigations of the Cu in 2.0 M HNO3 surface revealed that assembles protect Cu from corrosion by adsorption on its surfaces by a forming coating film. Clearly, the assembled mechanisms play a role as a barrier to corrosive solution.The corrosion hindrance of Cu in 2.0 M HNO3 solution by 2-amino-6-methyl-5-oxo-4-phenyl-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile compound has been studied, using Potentiodynamic Polarization (PP), AC Impedance (EIS), Electrochemical Frequency Modulation (EFM) techniques. Also, EIS test was utilized to confirm the corrosion protection mechanism. 2-amino-6-methyl-5-oxo-4-phenyl-5,6-dihydro-4H-pyrano[3,2-c]quinoline-3-carbonitrile compound is suggested as a mixed kind inhibitor. SEM and EDX investigations of the Cu in 2.0 M HNO3 surface revealed that assembles protect Cu from corrosion by adsorption on its surfaces by a forming coating film. Clearly, the assembled mechanisms play a role as a barrier to corrosive solution.

关 键 词：Carbonitrile Cu SEM EDX EIS EFM 

分 类 号：TG1[金属学及工艺—金属学]