Alkali Ionic Conductivity in Inorganic Glassy Electrolytes  

作　　者：Ram Krishna Hona Mandy Guinn Uttam S. Phuyal S’Nya Sanchez Gurjot S. Dhaliwal Ram Krishna Hona;Mandy Guinn;Uttam S. Phuyal;S’Nya Sanchez;Gurjot S. Dhaliwal(Department of Environmental Science, United Tribes Technical College, Bismarck, USA;School of Arts and Science, University of Mount Olive, Mount Olive, USA;Intertribal Research and Resource Center, United Tribes Technical College, Bismarck, USA)

机构地区：[1]Department of Environmental Science, United Tribes Technical College, Bismarck, USA [2]School of Arts and Science, University of Mount Olive, Mount Olive, USA [3]Intertribal Research and Resource Center, United Tribes Technical College, Bismarck, USA

出　　处：《Journal of Materials Science and Chemical Engineering》2023年第7期31-72,共42页材料科学与化学工程（英文）

摘　　要：Glassy electrolytes could be a potential candidate for all-solid-state batteries that are considered new-generation energy storage devices. As glasses are one of the potential fast ion-conducting electrolytes, progressive advances in glassy electrolytes have been undergoing to get commercial attention. However, the challenges offered by ionic conductivity at room temperature (10⁻⁵ - 10⁻³ S∙cm⁻¹) in comparison to those of organic liquid electrolytes (10⁻² S∙cm⁻¹) hindered the applicability of such electrolytes. To enhance the research development on ionic conductivity, the overall picture of the ionic conductivity of glassy electrolytes is reviewed in this article with a focus on alkali oxide and sulfide glasses. We portray here the techniques applied for alkali ion conductivity enhancement, such as methods of glass preparation, host optimization, doping, and salt addition for enhancing alkali ionic conductivity in the glasses.Glassy electrolytes could be a potential candidate for all-solid-state batteries that are considered new-generation energy storage devices. As glasses are one of the potential fast ion-conducting electrolytes, progressive advances in glassy electrolytes have been undergoing to get commercial attention. However, the challenges offered by ionic conductivity at room temperature (10⁻⁵ - 10⁻³ S∙cm⁻¹) in comparison to those of organic liquid electrolytes (10⁻² S∙cm⁻¹) hindered the applicability of such electrolytes. To enhance the research development on ionic conductivity, the overall picture of the ionic conductivity of glassy electrolytes is reviewed in this article with a focus on alkali oxide and sulfide glasses. We portray here the techniques applied for alkali ion conductivity enhancement, such as methods of glass preparation, host optimization, doping, and salt addition for enhancing alkali ionic conductivity in the glasses.

关 键 词：Glass Electrolyte Solid State Ionic Glass Battery Charge ANTIPEROVSKITE Ionic Conductivity 

分 类 号：O64[理学—物理化学]