Study of the Conversion of Postconsumer Polystyrene on CeO₂/HZSM-5 Type Materials  

作　　者：Mirna Oliveira Sant’Ana Anne Michelle Garrido Pedrosa Marcelo José Barros de Souza Mirna Oliveira Sant’Ana;Anne Michelle Garrido Pedrosa;Marcelo José Barros de Souza(Graduate Program in Chemical Engineering at UFS, Federal University of Sergipe (UFS), Sã,o Cristó,vã,o, Brazil;Department of Chemistry, Federal University of Sergipe, Sã,o Cristó,vã,o, Brazil)

机构地区：[1]Graduate Program in Chemical Engineering at UFS, Federal University of Sergipe (UFS), Sã,o Cristó,vã,o, Brazil [2]Department of Chemistry, Federal University of Sergipe, Sã,o Cristó,vã,o, Brazil

出　　处：《Journal of Materials Science and Chemical Engineering》2024年第4期29-41,共13页材料科学与化学工程（英文）

摘　　要：The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO₂, 10% CeO₂/HZSM-5 and 20% CeO₂/HZSM-5, which were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption at 77K. The catalytic tests were performed via thermogravimetric analysis (TG) at heating rates of 5, 10 and 20˚C min⁻¹ in a temperature range from 30˚C to 900˚C. For the tests, a ratio of 30% by mass of each catalytic material mixed with PS was used and the activation energy of the degradation process was determined by the Vyazovkin method. The obtained results showed that the addition of the catalyst to the PS in general reduced its degradation temperature. The 10% CeO₂/HZSM-5 catalyst showed greater efficiency, as it resulted in lower activation energy for PS degradation. Thus, the combination of CeO₂ with HZSM-5 resulted in materials with potential for application in the catalytic degradation of polystyrene and the results indicate that the production of a composite material can be a good strategy to generate an increase in catalytic activity and a decrease in energy process activation.The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO₂, 10% CeO₂/HZSM-5 and 20% CeO₂/HZSM-5, which were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption at 77K. The catalytic tests were performed via thermogravimetric analysis (TG) at heating rates of 5, 10 and 20˚C min⁻¹ in a temperature range from 30˚C to 900˚C. For the tests, a ratio of 30% by mass of each catalytic material mixed with PS was used and the activation energy of the degradation process was determined by the Vyazovkin method. The obtained results showed that the addition of the catalyst to the PS in general reduced its degradation temperature. The 10% CeO₂/HZSM-5 catalyst showed greater efficiency, as it resulted in lower activation energy for PS degradation. Thus, the combination of CeO₂ with HZSM-5 resulted in materials with potential for application in the catalytic degradation of polystyrene and the results indicate that the production of a composite material can be a good strategy to generate an increase in catalytic activity and a decrease in energy process activation.

关 键 词：HZSM-5 Zeolite Cerium Oxide POLYSTYRENE PYROLYSIS 

分 类 号：O64[理学—物理化学]