Some Salicylato New Organotin (IV) and Copper Chloride Adducts and Derivative: Synthesis and Spectroscopic Study  

作　　者：Boucar Diouf Waly Diallo Bocar Traoré Mamadou Sidibé Boucar Diouf;Waly Diallo;Bocar Traoré;Mamadou Sidibé(Dpartement de Chimie Laboratoire de Chimie Minrale et Analytique, Facult des Sciences et Techniques, Universit Cheikh Anta Diop de Dakar, Dakar, Sngal)

机构地区：[1]Dpartement de Chimie Laboratoire de Chimie Minrale et Analytique, Facult des Sciences et Techniques, Universit Cheikh Anta Diop de Dakar, Dakar, Sngal

出　　处：《Journal of Materials Science and Chemical Engineering》2024年第10期13-17,共5页材料科学与化学工程（英文）

摘　　要：Three new salicylate complexes and derivatives have been synthesized and studied by infrared, 119Sn NMR and UV-visible spectroscopies. The suggested structures for the two compounds are discrete with NH-O and NH-Cl hydrogen bonds. The salicylate oxyanion is monochelating for the first salicylate compound with an octahedral tin (IV) centre and monodentate for the second salicylate compound, the environments around the tin centre being tetrahedral. For the cooper complex, the salicylate ligand is monochelating and the environments around the copper atom centre are tetrahedral.Three new salicylate complexes and derivatives have been synthesized and studied by infrared, 119Sn NMR and UV-visible spectroscopies. The suggested structures for the two compounds are discrete with NH-O and NH-Cl hydrogen bonds. The salicylate oxyanion is monochelating for the first salicylate compound with an octahedral tin (IV) centre and monodentate for the second salicylate compound, the environments around the tin centre being tetrahedral. For the cooper complex, the salicylate ligand is monochelating and the environments around the copper atom centre are tetrahedral.

关 键 词：Discrete Structures Hydrogen Bonds Monochelating Monodentate Octahedral or Tetrahedral Environments 

分 类 号：O62[理学—有机化学]