Synthesis, Growth and Characterization of Benzophenone Added Sodium Acid Phthalate Crystal—A Potential Material for Nonlinear Optical Applications  

作　　者：Anandaraj Louis Jothi Lakshmanan Anandaraj Louis;Jothi Lakshmanan(PG & Research Department of Physics, Sacred Heart College (Autonomous), Tirupattur, Tamil Nadu, India;Periyar University, Palkalai Nagar, Salem, Tamil Nadu, India;PG & Research Department of Physics, Namakkal Kavignar Ramalingam Government Arts College for Women, Namakkal, Tamil Nadu, India)

机构地区：[1]PG & Research Department of Physics, Sacred Heart College (Autonomous), Tirupattur, Tamil Nadu, India [2]Periyar University, Palkalai Nagar, Salem, Tamil Nadu, India [3]PG & Research Department of Physics, Namakkal Kavignar Ramalingam Government Arts College for Women, Namakkal, Tamil Nadu, India

出　　处：《Journal of Minerals and Materials Characterization and Engineering》2022年第1期15-27,共13页矿物质和材料特性和工程（英文）

摘　　要：Sodium acid phthalate C₈H₅NaO₄ is one of the suitable semiorganic single crystals hired in second harmonic generation conversion applications. In the present work, optically transparent Benzophenone doped with sodium acid phthalate (SAPB) single crystals were grown successfully by slow evaporation solution technique. Single crystal XRD analyses exposed that the crystal lattice of SAPB crystal is a monoclinic crystal system with unit cell parameters <em>a</em> = 6.77 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, "font-size:40px;text-align:center;white-space:normal;background-color:#FFFFFF;"><span style="white-space:nowrap;">&#197;</span></span><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, "font-size:40px;text-align:center;white-space:normal;background-color:#FFFFFF;"></span></span></span>, <em>b </em>= 9.31 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&#197;</span></span></span>, <em>c</em> = 13.58 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&#197;</span></span></span>, and space group B2cb. The crystalline nature of SAPB material was confirmed by powder XRD pattern. The functional groups present in the grown crystals were identified by the FTIR analysis ranging between 4000 and 500 cm<sup><span style="white-space:nowrap;"><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, " font-size:40px;text-align:center;white-space:normal;background-color:#ffffff;"=""><span style="white-space:nowrap;">&#8722;</span></span><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFSodium acid phthalate C₈H₅NaO₄ is one of the suitable semiorganic single crystals hired in second harmonic generation conversion applications. In the present work, optically transparent Benzophenone doped with sodium acid phthalate (SAPB) single crystals were grown successfully by slow evaporation solution technique. Single crystal XRD analyses exposed that the crystal lattice of SAPB crystal is a monoclinic crystal system with unit cell parameters <em>a</em> = 6.77 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, "font-size:40px;text-align:center;white-space:normal;background-color:#FFFFFF;"><span style="white-space:nowrap;">&#197;</span></span><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, "font-size:40px;text-align:center;white-space:normal;background-color:#FFFFFF;"></span></span></span>, <em>b </em>= 9.31 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&#197;</span></span></span>, <em>c</em> = 13.58 <span style="white-space:nowrap;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">&#197;</span></span></span>, and space group B2cb. The crystalline nature of SAPB material was confirmed by powder XRD pattern. The functional groups present in the grown crystals were identified by the FTIR analysis ranging between 4000 and 500 cm<sup><span style="white-space:nowrap;"><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemFont, " font-size:40px;text-align:center;white-space:normal;background-color:#ffffff;"=""><span style="white-space:nowrap;">&#8722;</span></span><span class="color-dim" style="box-sizing:border-box;color:#636363;font-family:Montserrat, system-ui, -apple-system, BlinkMacSystemF

关 键 词：Growth from Solution UV-VIS FTIR Powder XRD Fluorescence SHG 

分 类 号：O17[理学—数学]