Synthesis, Crystal Structure and Thermal Behavior of a 3-D Barium(II)/Iron(III)-Oxalate Polymer  

作　　者：Noé Makon Ma Houga Brian S. Dolinar Justin Nenwa Gouet Bebga 

机构地区：[1]2124 Chemistry Department, University of Wisconsin-Madison, Madison, USA [2]Department of Chemistry, Higher Teacher Training College, University of Yaounde 1, Yaounde, Cameroon [3]Department of Inorganic Chemistry, University of Yaounde 1, Yaounde, Cameroon

出　　处：《Open Journal of Inorganic Chemistry》2014年第2期21-29,共9页无机化学期刊（英文）

摘　　要：Reaction of Ba(NO3)2 with Fe(NO3)3·9H2O and H2C2O4·2H2O in aqueous medium readily affords, in high yield, the bimetallic complex polymer of chemical composition {Ba6(H2O)17[Fe(C2O4)3]4}·7H2O (1), consistent with the expected ratio of 3BaII vs. 2FeIII. Compound 1 was fully characterized by elemental and thermal analyses, vibrational FTIR spectroscopy, and by single crystal X-ray structure determination. The bulk structure of 1 is a 3-D metal-organic framework held together by intermetallic linkages across oxalate and aqua oxygen bridgings. Thermal analyses of 1 show significant weight losses corresponding to water molecules (lattice and coordinated), followed by the decomposition of the network.Reaction of Ba(NO3)2 with Fe(NO3)3·9H2O and H2C2O4·2H2O in aqueous medium readily affords, in high yield, the bimetallic complex polymer of chemical composition {Ba6(H2O)17[Fe(C2O4)3]4}·7H2O (1), consistent with the expected ratio of 3BaII vs. 2FeIII. Compound 1 was fully characterized by elemental and thermal analyses, vibrational FTIR spectroscopy, and by single crystal X-ray structure determination. The bulk structure of 1 is a 3-D metal-organic framework held together by intermetallic linkages across oxalate and aqua oxygen bridgings. Thermal analyses of 1 show significant weight losses corresponding to water molecules (lattice and coordinated), followed by the decomposition of the network.

关 键 词：Tris(Oxalato)Ferrate(III) Anion Bimetallic Complex POLYMER Crystal Structure Thermal Stability 

分 类 号：O6[理学—化学]