Synthesis, Characterization and Antibacterial Activity of Mixed Ligand (HL) Complexes Mn(ll), Co(ll), Ni(ll), Zn(ll), Cd(ll) and Hg(ll) with Azide (N<sub>3</sub><sup style="margin-left:-6px;">-</sup>)  

Synthesis, Characterization and Antibacterial Activity of Mixed Ligand (HL) Complexes Mn(ll), Co(ll), Ni(ll), Zn(ll), Cd(ll) and Hg(ll) with Azide (N<sub>3</sub><sup style="margin-left:-6px;">-</sup>)

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作  者:Jassim S. Sultan Sajed M. Lateaf Dhuha K. Rashid 

机构地区:[1]Department of Chemistry, College of Education for pure Sciences, Ibn Al-Hiatham, University of Baghdad, Baghdad, Iraq

出  处:《Open Journal of Inorganic Chemistry》2015年第4期102-111,共10页无机化学期刊(英文)

摘  要:The complexes of mixed ligand (HL) as primary ligand with azide ion (N3-) as co-ligand with Mn(ll), Co(ll), Ni(ll), Zn(ll), Cd(ll) and Hg(ll) were prepared via reaction metal (ll) chloride salt with ligand (HL) and sodium azide (NaN3) using 1:2:2 mole ratio in ethanol solvent, respectively. The complexes of mixed ligand (HL) were characterized by elemental microanalysis (C.H.N), atomic absorption chloride content, molar conductance, magnetic susceptibility, melting point, FTIR and UV-Vis spectral data. The anti bacterial activity with four kinds of bacteria, Staphylococcus aureus, Bacillus, Escherichia coli and Pseudomonas aureus was studied.The complexes of mixed ligand (HL) as primary ligand with azide ion (N3-) as co-ligand with Mn(ll), Co(ll), Ni(ll), Zn(ll), Cd(ll) and Hg(ll) were prepared via reaction metal (ll) chloride salt with ligand (HL) and sodium azide (NaN3) using 1:2:2 mole ratio in ethanol solvent, respectively. The complexes of mixed ligand (HL) were characterized by elemental microanalysis (C.H.N), atomic absorption chloride content, molar conductance, magnetic susceptibility, melting point, FTIR and UV-Vis spectral data. The anti bacterial activity with four kinds of bacteria, Staphylococcus aureus, Bacillus, Escherichia coli and Pseudomonas aureus was studied.

关 键 词:4-AMINOANTIPYRINE Glyoxylic Acid Sodium AZIDE SCHIFF Base AZIDO Mixed Ligand 

分 类 号:O6[理学—化学]

 

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