Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C₆H₄(NH₃)₂Cl₂ (I), β-[C₆H₁₀N₂]₂ZnCl₄ (II), Respectively  

作　　者：Nejeh Hannachi Rim Elwej Thierry Roisnel Faouzi Hlel Nejeh Hannachi;Rim Elwej;Thierry Roisnel;Faouzi Hlel(Laboratory of Spectroscopic Characterization and Optics of Materials, Faculty of Sciences, University of Sfax, Sfax, Tunisia;National Center for Research in Materials Science (CNRSM), Laboratory for the Valorization of Useful Materials (LVMU), Borj Cedria, Tunisia;CNRS, ISCR (Institute of Chemical Sciences of Rennes), Université de Rennes, Rennes, France)

机构地区：[1]Laboratory of Spectroscopic Characterization and Optics of Materials, Faculty of Sciences, University of Sfax, Sfax, Tunisia [2]National Center for Research in Materials Science (CNRSM), Laboratory for the Valorization of Useful Materials (LVMU), Borj Cedria, Tunisia [3]CNRS, ISCR (Institute of Chemical Sciences of Rennes), Université de Rennes, Rennes, France

出　　处：《Open Journal of Inorganic Chemistry》2023年第1期1-24,共24页无机化学期刊（英文）

摘　　要：Two organic-inorganic hybrid materials, C₆H₄(NH₃)₂∙Cl₂ (I) and β-[C₆H₁₀N₂]₂ZnCl₄ (II), have been synthesized by hydrothermal method. These two materials are one of the hybrid materials have emerged as one of the most brilliant components classes. These extraordinary compounds synergistically combine the desired physical properties of both organic and inorganic components into a single compound offering the possibility to achieve great improvement over time in terms of science across various sectors. Their structures were determined by XRD pattern investigations and single crystal X-ray diffraction. These two compounds are crystallized in the monoclinic system;C2/c space group. In the both structures, the anionic-cationic entities are interconnected by hydrogen bonding contacts and p-p Interaction forming three-dimensional networks. Intermolecular interactions were investigated by Hirshfeld surfaces and the contacts of the four different chloride atoms in (II) were compared. The vibrational absorption bands were identified by infrared spectroscopy. These compounds were also investigated by solid state¹³C NMR spectroscopy.Two organic-inorganic hybrid materials, C₆H₄(NH₃)₂∙Cl₂ (I) and β-[C₆H₁₀N₂]₂ZnCl₄ (II), have been synthesized by hydrothermal method. These two materials are one of the hybrid materials have emerged as one of the most brilliant components classes. These extraordinary compounds synergistically combine the desired physical properties of both organic and inorganic components into a single compound offering the possibility to achieve great improvement over time in terms of science across various sectors. Their structures were determined by XRD pattern investigations and single crystal X-ray diffraction. These two compounds are crystallized in the monoclinic system;C2/c space group. In the both structures, the anionic-cationic entities are interconnected by hydrogen bonding contacts and p-p Interaction forming three-dimensional networks. Intermolecular interactions were investigated by Hirshfeld surfaces and the contacts of the four different chloride atoms in (II) were compared. The vibrational absorption bands were identified by infrared spectroscopy. These compounds were also investigated by solid state¹³C NMR spectroscopy.

关 键 词：Crystal Structure Hirshfeld Surface ¹³C NMR-MAS Vibration Absorption 

分 类 号：O62[理学—有机化学]