Investigation of the Petrological and Geochemical Characteristics of Siderite in the Early Cretaceous Sandstone of Lacustrine Sedimentary Sequence in the Erlian Basin from Northeastern China  

作　　者：Yunlong Zhang Mingming Tian Huili Xie Xide Li Wusheng Liu Shiqi Ni Yunlong Zhang;Mingming Tian;Huili Xie;Xide Li;Wusheng Liu;Shiqi Ni(Beijing Research Institute of Uranium Geology, Beijing, China)

机构地区：[1]Beijing Research Institute of Uranium Geology, Beijing, China

出　　处：《Journal of Geoscience and Environment Protection》2024年第6期305-321,共17页地球科学和环境保护期刊（英文）

摘　　要：Siderite is a prevalent authigenic mineral in siliciclastic rocks, which usually occurred in eodiagensis period and could be used as an indicator of sedimentary environment. Some siderite precipitated in burial depth with geochemical information of basin fluid evolution. The crystal morphology, geochemical composition, and isotope values are influenced by physical and geochemical environment of precipitation. In this study, samples from the Early Cretaceous of Erlian basin in the northwestern China were collected, and mineralogy, bulk and in-situ geochemistry, C and O isotopes were analyzed to comprehensively investigate the sedimentary and diagenetic environment that the sediments experienced. Six lithofaices with three types of crystal habits were recognized in the siderite-rich sandstone, bundle crystal in spherical forms, blocky rhombs in intergranular pore and cleavage of muscovite, and micro bundle and mosaic crystals aggregates in nodular. The siderite growth proceeds through micro bundle and mosaic crystals to bundle siderite aggregates and then into blocky rhombs. The crystal evolution is also reflected by geochemical composition. The micro bundle and mosaic crystals are Casiderite. The spheritic shaped bundle aggregates are Ca-Mn-siderite. The blocky rhomb siderite shows gray part and bight part with Ca, Mg and Mn varies. Increase of Ca in block rhomb siderite suggests burial and mesodiagenesis, the high content of Mn may have linkage with eogenetic effects. The relatively positive and slightly negative δ13C value indicates meteoric water domination and influence of organic matter evolution in shallow buried time. The narrow ranges negative δ18O value suggest a small span of temperature of siderite formation.Siderite is a prevalent authigenic mineral in siliciclastic rocks, which usually occurred in eodiagensis period and could be used as an indicator of sedimentary environment. Some siderite precipitated in burial depth with geochemical information of basin fluid evolution. The crystal morphology, geochemical composition, and isotope values are influenced by physical and geochemical environment of precipitation. In this study, samples from the Early Cretaceous of Erlian basin in the northwestern China were collected, and mineralogy, bulk and in-situ geochemistry, C and O isotopes were analyzed to comprehensively investigate the sedimentary and diagenetic environment that the sediments experienced. Six lithofaices with three types of crystal habits were recognized in the siderite-rich sandstone, bundle crystal in spherical forms, blocky rhombs in intergranular pore and cleavage of muscovite, and micro bundle and mosaic crystals aggregates in nodular. The siderite growth proceeds through micro bundle and mosaic crystals to bundle siderite aggregates and then into blocky rhombs. The crystal evolution is also reflected by geochemical composition. The micro bundle and mosaic crystals are Casiderite. The spheritic shaped bundle aggregates are Ca-Mn-siderite. The blocky rhomb siderite shows gray part and bight part with Ca, Mg and Mn varies. Increase of Ca in block rhomb siderite suggests burial and mesodiagenesis, the high content of Mn may have linkage with eogenetic effects. The relatively positive and slightly negative δ13C value indicates meteoric water domination and influence of organic matter evolution in shallow buried time. The narrow ranges negative δ18O value suggest a small span of temperature of siderite formation.

关 键 词：SIDERITE Sedimentary Environment Lacustrine Deposition Early Cretaceous Erlian Basin 

分 类 号：P59[天文地球—地球化学]