TERBIUM

作品数：169被引量：209H指数：6
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Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline)tetradentate ligands
《Chinese Journal of Structural Chemistry》2024年第9期46-51,共6页Hao Jiang Yuan-Yuan He Hai-Chao Liang Meng-Jia Shang Han-Han Lu Chun-Hua Liu Yin-Shan Meng Tao Liu Yuan-Yuan Zhu 
supported by the National Natural Science Foundation of China(Nos.22371063,22222103,22173015,22025101,and 91961114);the State Key Laboratory of Fine Chemicals at Dalian University of Technology(KF 1607);the Fundamental Research Funds for the Central Universities of China(PA2021GDSK0063,DUT22LAB606).
Organic ligands play a pivotal role in lanthanide luminescence by acting as sensitizers for energy absorption and transfer,a phenomenon known as the fluorescence antenna effect.Herein,we introduce two tetradentate nit...
关键词：LANTHANIDE Luminescence Antenna effect EUROPIUM TERBIUM 
Tetravalent Terbium Chelates: Stability Enhancement and Property Tuning
《Precision Chemistry》2023年第10期583-591,共9页Tianjiao Xue You-Song Ding Xue-Lian Jiang Lizhi Tao Jun Li Zhiping Zheng 
supported by the National Natural Science Foundation of China(92261203,22101116,22033005 and 21971106);Key Laboratory of Rare Earth Chemistry of Guangdong Higher Education Institutes(2022KSYS006);the Stable Support Plan Program of Shenzhen Natural Science Fund(20200925161141006),Shenzhen Fundamental Research Program(JCYJ20220530115001002);Postdoctoral Scientific Research Fund for staying at(coming to)Shenzhen(K21217520);The calculations were performed with SUSTech supercomputer and were supported by Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002).
Coordination chemistry of rare-earth elements has been dominated by the+3 oxidation state.Complexes with higher-valence lanthanide ions are synthetically challenging but are of fundamental research interest and signif...
关键词：Tetravalent Terbium Ion Chelating Ligand Formal Potential STABILITY Magnetic Property 
A Terbium(Ⅲ)-organic Coordination Polymer:Synthesis,Characterization and Its Luminescence
《Chinese Journal of Structural Chemistry》2022年第2期79-84,I0009,共7页MI Ying-Hao YANG Ming-Xue KUANG Xiao-Fei LU Can-Zhong 
supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033);the National Natural Science Foundation of China(52073286,21875252,21701177);the Natural Science Foundation of Fujian Province(2006L2005)。
A new 3D terbium(Ⅲ)metal-organic network[Tb(HIMDC)(HCOO)(H_(2)O)]_(n)(complex 1)has been synthesized by Tb^(3+)ions coordinated with 4,5-imidazole dicarboxylic acid(H_(3)IMDC)and formic acid under solvothermal condit...
关键词：coordination polymer crystal structure PHOTOLUMINESCENCE 
A stoichiometric terbium-europium dyad molecular thermometer: energy transfer properties被引量：4
《Light(Science & Applications)》2018年第1期141-150,共10页Guochen Bao Ka-Leung Wong Dayong Jin Peter A.Tanner 
grants from The Hong Kong Research Grants Council(HKBU 22301615);from Hong Kong Baptist University(FRG 2/17-18/007).
The optical thermometer has shown great promise for use in the fields of aeronautical engineering,environmental monitoring and medical diagnosis.Self-referencing lanthanide thermo-probes distinguish themselves because...
关键词：temperature. LANTHANIDE transfer 
A New Terbium(Ⅲ) Coordination Compound with 2-Thiophenecarboxylic Ligand:Synthesis and Crystal Structure被引量：2
《Chinese Journal of Structural Chemistry》2014年第7期1013-1018,共6页赵振新 马步伟 任国建 章应辉 
Supported by Henan Province Key Scientific Research Projects(122102210395);Pingdingshan Key Scientific Research Projects(No.2013066)
A new coordination compound with formula [Tb（2-TC）3（DMF）]n （1, 2-TC = 2-thio- phenecarboxylic ligand and DMF = dimethylformamide） was synthesized by solvothermal method. The structure of compound 1 was determine...
关键词：2-thiophenecarboxylic acid terbium（III） crystal structure 
Synthesis, Structure and Luminescent Properties of a New Terbium(Ⅲ) Complex with 5-Bromoisophthalic Acid被引量：8
《Chinese Journal of Structural Chemistry》2012年第2期173-178,共6页刘光祥 查筱春 李杏龙 
Supported by the National Natural Science Foundation of China (No. 20971004);the Key Project of Chinese Ministry of Education (No. 210102)
The self-assembly of 5-bromoisophthalic acid （H2BIPA） with Tb（NO3）3·6H2O under hydrothermal conditions gives rise to a 3D coordination polymer, [Tb2（BIPA）3（CH3CH2OH）]n （1）, which was characterized by elemen...
关键词：Tb（Ⅲ） coordination polymer crystal structure 5-bromoisophthalic acid LUMINESCENCE 
Synthesis,crystal structure and characterization of one-dimension complex constructed by terbium(Ⅲ) and 2-iodobenzoate被引量：1
《Journal of Rare Earths》2009年第3期373-376,共4页许丽娟 李艳秋 李夏 
supported by the Natural Science Foundation of Beijing (2073022)
The complex of [Tb（2-IBA）3（H2O）2]n （2-IBA=2-iodobenzoate） was prepared by solvent method from TbCl3-6H2O and 2-iodobenzoic acid. The crystal structure was determined with X-ray single-crystal diffraction. The X-...
关键词：terbium complex 2-iodobenzoic acid crystal structure fluorescence rare earths 
One-dimensional Supramolecular Chain Based on a Dinuclear Terbium(Ⅲ) 4-Cyanobenzoate Complex被引量：1
《Chinese Journal of Structural Chemistry》2007年第7期805-810,共6页李国清 李艳 邹文强 陈其湧 吴阿清 郑发鲲 郭国聪 
the National Natural Science Foundation of China (20671091) ;Natural Science of Fujian Province (A0420002 and 2005I017)
A new dinuclear Tb（Ⅲ） 4-cyanobenzoate complex [Tb2（4-cba）6（phen）2] （4-Hcba = 4-cyanobenzoic acid and phen = 1,10-phenanthroline） 1 has been synthesized by solvothermal reaction in an ethanol/water mixed solut...
关键词：terbium（Ⅲ） complex 4-cyanobenzoic add crystal structure π-π stacking optical spectroscopy 
Synthesis and Crystal Structure of A Bimetallic Terbium Complex Tb2 {μ-CH2 SiMe2 NC6 H3 ^iPr2 -2, 6}3 （THF）3
《Journal of Rare Earths》2007年第5期554-557,共4页罗云杰 陈珏 毛红雷 
Project supported by the National Natural Science Foundation of China (20604023);Zhejiang Provincial Natural Science Foundation (Y406301)
The reaction of 2, 6-^iPr2CbH3NHSiMe3 with Tb（CH2SiMe3）3（THF）2 in benzene at room temperature afforded a binuclear terbium complex Tb2 {μ-CH2 SiMe2 NC6 H3 ^iPr2 -2, 6}3（THF）3. X-ray diffraction revealed that Tb...
关键词：TERBIUM BIMETALLIC arylamido ligand crystal structure rare earths 
Synthesis, Characterization and Fluorescence of Terbium(Ⅲ) Complexes with Phenylglyoxylic Acid and 2,2-Dipyridine, 1,10-Phenanthroline, Triphenyl Phosphine Oxide被引量：2
《Journal of Rare Earths》2006年第2期146-149,共4页张彦辉 颜剑波 裴娟 耿啸天 王云友 孙波 
Three new complexes TbL3dipy （H2O）2, TbL3phen （H2O） 2 and TbL2 （TPPO） 2NO3 were synthesized （L = phenylglyoxylate ion, dipy = 2, 2-dipyridine, phen = 1,10-phenanthmline, TPPO = Triphenyl phosphine oxide）. Elem...
关键词：TERBIUM COMPLEXES phenylglyoxylic acid IR spectra fluorescence spectra rare earths 
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