CYANO-BRIDGED

作品数:17被引量:8H指数:2
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相关领域:理学更多>>
相关期刊:《Progress in Natural Science:Materials International》《Chinese Journal of Chemistry》《Science China Chemistry》《无机化学学报》更多>>
相关基金:国家自然科学基金中国博士后科学基金国家重点基础研究发展计划福建省自然科学基金更多>>
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A Novel 3D Heterobimetallic Cyano-bridged Coor- dination Polymer {(NH_4)_2[Cd(H_2O)Fe(CN)_6]}_n:Synthesis and Crystal Structure
《Chinese Journal of Structural Chemistry》2014年第7期990-994,共5页曲景艳 莫宗巧 孙亚秋 
supported by the National Natural Science Foundation of China(No.20771083)
A novel heterobimetaUic coordination polymer, {(NH4)2[Cd(H20)Fe(CN)6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, 1R spectroscopy and single...
关键词:cyano-bridged complex crystal structure heterobimetallic coordination polymer 
Two bimetallic W(Ⅳ)-Mn(Ⅱ) complexes based on octacyanometallates:structures and magnetic properties被引量:4
《Science China Chemistry》2009年第11期1801-1807,共7页LIU BaoLin,XIAO HongPing,SONG You & YOU XiaoZeng State Key Laboratory of Coordination Chemistry,Nanjing National Laboratory of Microstructures,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China 
Supported by the National Natural Science Foundation of China (Grant Nos. 20771057, 20721002 and 20631030);the Major State Basic Research Develop-ment Program (Nos.2006CB806104 and 2007CB925102)
Two cyano-bridged heterobimetallic coordination polymers,[{Mn(dpa)2}2W(CN)8·CH3CN·4H2O]n(1)(dpa = 2,2'-dipyridylamine) and [Mn2(H2O)4{W(CN)8}·3H2O]n(2),have been synthesized and characterized structurally and magne...
关键词:CYANO-BRIDGED COORDINATION polymer magnetic property manganese(Ⅱ) complex 
Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ln(DMSO)_2(H_2O)(μ-CN)_4Fe(CN)_2] (Ln = Ce and Eu, DMSO = Dimethylsulfoxide) with Layered Structure
《Chinese Journal of Structural Chemistry》2008年第6期753-756,共4页赵振乾 蔡丽珍 陈文通 郭国聪 黄锦顺 
Financially supported by the NSF for Distinguished Young Scientist of China (20425104);the NSF of Fujian Province (E0510028, E0510029)
Two new bimetallic cyano-bridged complexes [Ln(DMSO)2(H2O)(μ-CN)4Fe(CN)2] (Ln = Ce 1, Eu 2) have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structur...
关键词:crystal structure cyano-bridged bimetallic complex grinding reaction method 
Synthesis and Structural Characterization of a Cyano-bridged 1-D Lanthanum(Ⅲ)-iron(Ⅲ) Complex [La(DMSO)_5(H_2O)](μ-CN)_2[Fe(CN)_4]·H_2O
《Chinese Journal of Structural Chemistry》2007年第10期1239-1242,共4页陈文通 郭国聪 蔡丽珍 陈惠芬 徐刚 黄锦顺 
the NNSFC (20571075, 20521101);the NSF for Distinguished Young Scientist of China (20425104);the NSF of Fujian Province (E0510028)
ABSTRACT A new lanthanumm-ironm complex [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4]·H2O 1 (DMSO = dimethylsulfoxide) has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction...
关键词:crystal structure CYANO-BRIDGED lanthanum complex Prussian blue 
Cyano-bridged Ln^3+-Cr^3+ Binuclear Complexes [Ln(L)x(H2O)y^- Cr(CN)6]·mL·nH2O (Ln=La-Nd, x=5, y=2, m=1 or 2, n=2 or 2.5; Ln-Sm-Dy, Er, x=4, y=3, m=0, n=1.5 or 2.0; L= 2-pyrrolidinone): Structure, Magnetism and Spin Density Map
《Chinese Journal of Chemistry》2007年第3期329-336,共8页孙献茹 陈志达 王明伟 王炳武 阎峰 CHEUNG Kung-Kai 
Project supported by the National Basic Research Program of China (No. 2006CB601102), the National Natural Science Foundation of China (Nos 20503001, 20490210, NSFC/RGC 20318001), the Doctoral Program Foundation of Education Minister (No. 20030001066).
In order to shed light upon the nature and mechanism of 4f-3d magnetic exchange interactions, a series of binuclear complexes of lanthanide(3+) and chromium(3+) with the general formula [Ln(L)5(H2O)2Cr(CN...
关键词:cyano-bridged compound 4f-3d magnetic coupling Ln-Cr spin density magnetic property 
Syntheses and Crystal Structures of Two Cyano-bridged Bimetallic Complexes [Ce(DMSO)_4(H_2O)_3Fe(CN)_6]·H_2O and [La(DMSO)_4(H_2O)_3Co(CN)_6]·H_2O(DMSO = Dimethylsulfoxide)
《Chinese Journal of Structural Chemistry》2006年第12期1481-1486,共6页赵振乾 陈文通 刘玺 蔡丽珍 郭国聪 黄锦顺 
This work was supported by the NNSFC (20571075), the NSF for Distinguished Young Scientist of China (20425104) and the NSF of Fujian Province (E0510028)
Two new bimetallic cyano-bridged complexes [Ce(DMSO)4(H2O)3Fe(CN)6]·H2O 1 and [La(DMSO)4(H20)3Co(CN)6].H20 2 have been prepared by the ball milling reaction method and structurally characterized by X-ray ...
关键词:crystal structure eyano-bridged bimetallic complex hydrogen bond lanthanide complex 
Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex[La(betaine)_2(H_2O)_6Fe(CN)_6]·2H_2O
《Chinese Journal of Structural Chemistry》2005年第4期424-428,共5页LIANGShu-Hui CHEYun-Xia ZHENGJi-Min 
Supported by the National Natural Science Foundation of China (No. 50242001)
The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21...
关键词:crystal structure SYNTHESIS cyano-bridged bimetallic complex hydrogen bond 
Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Complex K_3(TMS)_2(H_2O)_2Cr(CN)_6[TMS = Tetramethylene Sulfone]
《Chinese Journal of Structural Chemistry》2005年第4期379-382,共4页CHENWei CHEYun-Xia ZHENGJi-Min 
Supported by the Innovation Foundation for College Students of Nankai University and the National Natural Science Foundation of China (No. 50242001)
The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, sp...
关键词:crystal structure synthesis tetramethylene sulfone cyano-bridge 
Synthesis and Crystal Structure of a Cyano- bridged Bimetallic Complex[La(DMSO)_3(H_2O)_3- Cr(CN)_6]·H_2O (DMSO = Dimethylsulfoxide) with One-dimensional Chain Molecular Structure
《Chinese Journal of Structural Chemistry》2004年第11期1226-1229,共4页梁淑惠 车云霞 郑吉民 
This work was supported by the National Natural Science Foundation of China (No. 50242001)
The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with...
关键词:crystal structure synthesis cyano-bridged bimetallic complex hydrogen bond 
Synthesis and Structural Characterization of a Cyano-bridged Dinuclear Neodymium(III)-iron(III) Complex [Nd(DMSO)_5(H_2O)_2](μ-CN)[Fe(CN)_5]
《Chinese Journal of Structural Chemistry》2004年第11期1282-1286,共5页CHENWen-Tong CAILi-Zhen WUA-Qing GUOGuo-Cong HUANGJin-Shun 
The project was supported by NNSFC (20001007; 20131020) and NSF of the Chinese Academy of Sciences (KJCX2-H3) and Fujian Province (2000F006)
A new neodymiumIII-ironIII complex [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] (DMSO = dimethyl sulfoxide) has been synthesized by the grinding reaction method. The crystal belongs to monoclinic, space group P21/m with a = 8....
关键词:crystal structure cyano-bridged dinuclear complex neodymium complex iron complex 
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