supported by the National Natural Science Foundation of China(No.20771083)
A novel heterobimetaUic coordination polymer, {(NH4)2[Cd(H20)Fe(CN)6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, 1R spectroscopy and single...
Supported by the National Natural Science Foundation of China (Grant Nos. 20771057, 20721002 and 20631030);the Major State Basic Research Develop-ment Program (Nos.2006CB806104 and 2007CB925102)
Two cyano-bridged heterobimetallic coordination polymers,[{Mn(dpa)2}2W(CN)8·CH3CN·4H2O]n(1)(dpa = 2,2'-dipyridylamine) and [Mn2(H2O)4{W(CN)8}·3H2O]n(2),have been synthesized and characterized structurally and magne...
Financially supported by the NSF for Distinguished Young Scientist of China (20425104);the NSF of Fujian Province (E0510028, E0510029)
Two new bimetallic cyano-bridged complexes [Ln(DMSO)2(H2O)(μ-CN)4Fe(CN)2] (Ln = Ce 1, Eu 2) have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structur...
the NNSFC (20571075, 20521101);the NSF for Distinguished Young Scientist of China (20425104);the NSF of Fujian Province (E0510028)
ABSTRACT A new lanthanumm-ironm complex [La(DMSO)5(H2O)](μ-CN)2[Fe(CN)4]·H2O 1 (DMSO = dimethylsulfoxide) has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction...
Project supported by the National Basic Research Program of China (No. 2006CB601102), the National Natural Science Foundation of China (Nos 20503001, 20490210, NSFC/RGC 20318001), the Doctoral Program Foundation of Education Minister (No. 20030001066).
In order to shed light upon the nature and mechanism of 4f-3d magnetic exchange interactions, a series of binuclear complexes of lanthanide(3+) and chromium(3+) with the general formula [Ln(L)5(H2O)2Cr(CN...
This work was supported by the NNSFC (20571075), the NSF for Distinguished Young Scientist of China (20425104) and the NSF of Fujian Province (E0510028)
Two new bimetallic cyano-bridged complexes [Ce(DMSO)4(H2O)3Fe(CN)6]·H2O 1 and [La(DMSO)4(H20)3Co(CN)6].H20 2 have been prepared by the ball milling reaction method and structurally characterized by X-ray ...
Supported by the National Natural Science Foundation of China (No. 50242001)
The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21...
Supported by the Innovation Foundation for College Students of Nankai University and the National Natural Science Foundation of China (No. 50242001)
The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, sp...
This work was supported by the National Natural Science Foundation of China (No. 50242001)
The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with...
The project was supported by NNSFC (20001007; 20131020) and NSF of the Chinese Academy of Sciences (KJCX2-H3) and Fujian Province (2000F006)
A new neodymiumIII-ironIII complex [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] (DMSO = dimethyl sulfoxide) has been synthesized by the grinding reaction method. The crystal belongs to monoclinic, space group P21/m with a = 8....