the National Natural Science Foundation of China(No.21472153);the National Basic Research Program(973 Program)of China(No.2010CB833200);the SKL of Xiamen University(No.201509);the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education,China,for financial support
We describe the design and execution of a novel synthetic route to the tricyclic core of haliclonin A,a tetracyclic marine natural product.The approach features Bachi's thiol-medicated free radical cyclization of alk...