supported by the National Natural Science Foundation of China(No.21373043)
Three new polyoxometalates K2[H2(As3O3)2(Mo6O18)(NiO6)]?H2O (1), K2[H2-(As3O3)2(Mo6O18)(CoO6)]?H2O (2) and [Zn(H4,4?-bpy)2(H2O)4][(As3O3)2(Mo6O18)(ZnO6)]?4H2O (3) (4,4?-bpy = 4,4?-bi...
Supported by the National Natural Science Fund for Distinguished Young Scholars of China (No. 20725101);the 973 Program (No. 2006CB932904);the NSF of Fujian Province (No. E0510030);the Knowledge Innovation Program of CAS (No. KJCX2.YW.H01);the NNSFC (No. 20821061)
One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic propert...