This work was supported by Syngenta Postgraduate Fellowship,National Basic Research Program of China(No.2010CB126106);the National Key Technologies R&D Program(No.2011BAE06B05).
Due to a novel mode action,low toxicity to mammals and low residue characteristics,phthalic acid diamides have aroused considerable interests in agricultural chemistry.With introduction of N-cyano,N-trifluoroacetyl,N-...
This work was financially supported by the National Basic Research Program of China(973 Program,No.2010CB126100);the National High Technology Research and Development Program of China(863 Program Program,No.2011AA10A207);the National Natural Science Foundation of China(Nos.21372079;21272071);This work was also partly supported by the National Key Technology R&D Program of China(No.2011BAE06B01)and the Fundamental Research Funds for the Central Universities.
A series of novel phthalic diamide derivatives containing 1,2,3-triazole moiety were synthesized using one-pot click chemistry approach and characterized by ^(1)H NMR and HRMS.The insecticidal activity against armywor...
Two series of novel anthranilic diamide insecticide containing trifluoroethyl ether were designed and synthesized, and their structures were characterized by 1H NMR spectroscopy, elemental analysis and single crystal ...
Project supported by the National Natural Science Foundation of China (No. 20472063).
The reactions of dilithium salt of trans-1,2-bis(trimethylsilylamino)cyclohexane with anhydrous lanthanide trichlorides LnCl3 (Ln = Yb, Nd) in THF afforded the dianionic binuclear tricycles of lanthanide chlorides...
Project-supported by the National Natural Science Foundation of China (No. 20472063).
The reaction of anhydrous YbCl3 with 1 equiv, of Li2Me2Si(NPh)2 in THF, after workup, yielded a ytterbium(Ⅲ) chloride [{Me2Si(NPh)2Yb}(μ2-CI)(TMEDA)]2·3PhMe (1) (TMEDA=tetramethylethanediamine). The s...
Project supported by the National Natural Science Foundation of China (No. 20272044).
Three new A,C-diamide bridged p-tert-butylcalix[6]arenes were synthesized from p-tert-butylcalix[6]arenes by bridging ClCH2CONH(CH2)nNHCOCH2Cl (n=3, 4, 6) in acetonitrile using K2CO3 as a base in 17%—25% yields. It w...
Project (No.29775025) supported by the National Natural Science Foundation of China.
In this paper, the enthalpy-entropy compensation effect in the enantiomeric separation by modified cyclodextrins (CD) and diamide chiral stationary phase (GP) gas chromatography was investigated using the method of pl...